Palladium-catalyzed oxidative cross-coupling reaction of arylboronic acids with diazoesters for stereoselective synthesis of (E)-α,β- diarylacrylates

Yuk Tai Tsoi; Zhongyuan Zhou; Albert S.C. Chan; Wing Yiu Yu

doi:10.1021/ol101796t

Palladium-catalyzed oxidative cross-coupling reaction of arylboronic acids with diazoesters for stereoselective synthesis of (E)-α,β- diarylacrylates

Yuk Tai Tsoi, Zhongyuan Zhou, Albert S.C. Chan, Wing Yiu Yu

Research output: Journal article publication › Journal article › Academic research › peer-review

68 Citations (Scopus)

Abstract

A Pd-catalyzed oxidative cross-coupling reaction of arylboronic acids with α-diazoesters was achieved using molecular oxygen as the sole reoxidant, and E-α,β-diarylacrylates were obtained in good yields and >20:1 E-to-Z selectivity.

Original language	English
Pages (from-to)	4506-4509
Number of pages	4
Journal	Organic Letters
Volume	12
Issue number	20
DOIs	https://doi.org/10.1021/ol101796t
Publication status	Published - 15 Oct 2010

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol101796t

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title = "Palladium-catalyzed oxidative cross-coupling reaction of arylboronic acids with diazoesters for stereoselective synthesis of (E)-α,β- diarylacrylates",

abstract = "A Pd-catalyzed oxidative cross-coupling reaction of arylboronic acids with α-diazoesters was achieved using molecular oxygen as the sole reoxidant, and E-α,β-diarylacrylates were obtained in good yields and >20:1 E-to-Z selectivity.",

author = "Tsoi, {Yuk Tai} and Zhongyuan Zhou and Chan, {Albert S.C.} and Yu, {Wing Yiu}",

year = "2010",

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doi = "10.1021/ol101796t",

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Palladium-catalyzed oxidative cross-coupling reaction of arylboronic acids with diazoesters for stereoselective synthesis of (E)-α,β- diarylacrylates. / Tsoi, Yuk Tai; Zhou, Zhongyuan; Chan, Albert S.C. et al.
In: Organic Letters, Vol. 12, No. 20, 15.10.2010, p. 4506-4509.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

T1 - Palladium-catalyzed oxidative cross-coupling reaction of arylboronic acids with diazoesters for stereoselective synthesis of (E)-α,β- diarylacrylates

AU - Tsoi, Yuk Tai

AU - Zhou, Zhongyuan

AU - Chan, Albert S.C.

AU - Yu, Wing Yiu

PY - 2010/10/15

Y1 - 2010/10/15

N2 - A Pd-catalyzed oxidative cross-coupling reaction of arylboronic acids with α-diazoesters was achieved using molecular oxygen as the sole reoxidant, and E-α,β-diarylacrylates were obtained in good yields and >20:1 E-to-Z selectivity.

AB - A Pd-catalyzed oxidative cross-coupling reaction of arylboronic acids with α-diazoesters was achieved using molecular oxygen as the sole reoxidant, and E-α,β-diarylacrylates were obtained in good yields and >20:1 E-to-Z selectivity.

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U2 - 10.1021/ol101796t

DO - 10.1021/ol101796t

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SP - 4506

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JO - Organic Letters

JF - Organic Letters

IS - 20

ER -

Palladium-catalyzed oxidative cross-coupling reaction of arylboronic acids with diazoesters for stereoselective synthesis of (E)-α,β- diarylacrylates

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