Abstract
They make a good couple: Catalysts generated from Pd (OAc)2and indolylphosphine ligands are highly effective in the titanium-mediated coupling of aryl halides. Catalyst loadings as low as 0.05 mol % Pd can be used. The mild reaction conditions also allow the coupling of aryl sulfonyl chlorides with aryl titanium reagents to generate diaryl sulfones. KGaA.
Original language | English |
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Pages (from-to) | 7436-7439 |
Number of pages | 4 |
Journal | Angewandte Chemie - International Edition |
Volume | 48 |
Issue number | 40 |
DOIs | |
Publication status | Published - 21 Sept 2009 |
Keywords
- Cross-coupling
- Palladium
- Phosphanes
- Sulfones
- Titanium
ASJC Scopus subject areas
- Catalysis
- General Chemistry