Oxo-ruthenium(V) complexes of macrocyclic tetradentate tertiary amines that function as active electrochemical oxidative catalysts, and X-ray crystal structure of trans-[RuIV(tmc)O(CI)]CIO4(tmc = 1,4,8,11 -tetramethyl-1,4,8,1 I-tetra-azacyclotetradecane)

Chi Ming Che; Kwok Yin Wong; Thomas C.W. Mak

doi:10.1039/C39850000988

Oxo-ruthenium(V) complexes of macrocyclic tetradentate tertiary amines that function as active electrochemical oxidative catalysts, and X-ray crystal structure of trans-[Ru^IV(tmc)O(CI)]CIO₄(tmc = 1,4,8,11 -tetramethyl-1,4,8,1 I-tetra-azacyclotetradecane)

Chi Ming Che
, Kwok Yin Wong
, Thomas C.W. Mak

Research output: Journal article publication › Journal article › Academic research › peer-review

65 Citations (Scopus)

Abstract

Ruthenium(v) mono-oxo complexes electrochemically generated from trans-[Ru^IVLO(CI)]⁺(L = tmc or 15 -tmc; tmc = 1,4,8,11 -tetramethyI-1,4,8,11 -tetra-azacyclotetradecane, 15-tmc = 1,4,8,12-tetramethyl-1,4,8,12-tetraazacyclopentadecane) are active oxidative catalysts for the conversion of alcohol into aldehyde; X-ray analysis of trans-[Ru^IV(tmc)O(CI)]CIO₄ yielded Ru=O 1.765(7) Å, and Ru-CI 2.505(3) Å.

Original language	English
Pages (from-to)	988-990
Number of pages	3
Journal	Journal of the Chemical Society - Series Chemical Communications
Issue number	14
DOIs	https://doi.org/10.1039/C39850000988
Publication status	Published - 1 Jan 1985
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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10.1039/C39850000988

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Che, C. M., Wong, K. Y., & Mak, T. C. W. (1985). Oxo-ruthenium(V) complexes of macrocyclic tetradentate tertiary amines that function as active electrochemical oxidative catalysts, and X-ray crystal structure of trans-[Ru^IV(tmc)O(CI)]CIO₄(tmc = 1,4,8,11 -tetramethyl-1,4,8,1 I-tetra-azacyclotetradecane). Journal of the Chemical Society - Series Chemical Communications, (14), 988-990. https://doi.org/10.1039/C39850000988

Che, Chi Ming ; Wong, Kwok Yin ; Mak, Thomas C.W. / Oxo-ruthenium(V) complexes of macrocyclic tetradentate tertiary amines that function as active electrochemical oxidative catalysts, and X-ray crystal structure of trans-[Ru^IV(tmc)O(CI)]CIO₄(tmc = 1,4,8,11 -tetramethyl-1,4,8,1 I-tetra-azacyclotetradecane). In: Journal of the Chemical Society - Series Chemical Communications. 1985 ; No. 14. pp. 988-990.

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title = "Oxo-ruthenium(V) complexes of macrocyclic tetradentate tertiary amines that function as active electrochemical oxidative catalysts, and X-ray crystal structure of trans-[RuIV(tmc)O(CI)]CIO4(tmc = 1,4,8,11 -tetramethyl-1,4,8,1 I-tetra-azacyclotetradecane)",

abstract = "Ruthenium(v) mono-oxo complexes electrochemically generated from trans-[RuIVLO(CI)]+(L = tmc or 15 -tmc; tmc = 1,4,8,11 -tetramethyI-1,4,8,11 -tetra-azacyclotetradecane, 15-tmc = 1,4,8,12-tetramethyl-1,4,8,12-tetraazacyclopentadecane) are active oxidative catalysts for the conversion of alcohol into aldehyde; X-ray analysis of trans-[RuIV(tmc)O(CI)]CIO4 yielded Ru=O 1.765(7) {\AA}, and Ru-CI 2.505(3) {\AA}.",

author = "Che, \{Chi Ming\} and Wong, \{Kwok Yin\} and Mak, \{Thomas C.W.\}",

year = "1985",

month = jan,

day = "1",

doi = "10.1039/C39850000988",

language = "English",

pages = "988--990",

journal = "Journal of the Chemical Society - Series Chemical Communications",

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publisher = "Royal Society of Chemistry",

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Che, CM, Wong, KY & Mak, TCW 1985, 'Oxo-ruthenium(V) complexes of macrocyclic tetradentate tertiary amines that function as active electrochemical oxidative catalysts, and X-ray crystal structure of trans-[Ru^IV(tmc)O(CI)]CIO₄(tmc = 1,4,8,11 -tetramethyl-1,4,8,1 I-tetra-azacyclotetradecane)', Journal of the Chemical Society - Series Chemical Communications, no. 14, pp. 988-990. https://doi.org/10.1039/C39850000988

Oxo-ruthenium(V) complexes of macrocyclic tetradentate tertiary amines that function as active electrochemical oxidative catalysts, and X-ray crystal structure of trans-[Ru^IV(tmc)O(CI)]CIO₄(tmc = 1,4,8,11 -tetramethyl-1,4,8,1 I-tetra-azacyclotetradecane). / Che, Chi Ming; Wong, Kwok Yin; Mak, Thomas C.W.
In: Journal of the Chemical Society - Series Chemical Communications, No. 14, 01.01.1985, p. 988-990.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

T1 - Oxo-ruthenium(V) complexes of macrocyclic tetradentate tertiary amines that function as active electrochemical oxidative catalysts, and X-ray crystal structure of trans-[RuIV(tmc)O(CI)]CIO4(tmc = 1,4,8,11 -tetramethyl-1,4,8,1 I-tetra-azacyclotetradecane)

AU - Che, Chi Ming

AU - Wong, Kwok Yin

AU - Mak, Thomas C.W.

PY - 1985/1/1

Y1 - 1985/1/1

N2 - Ruthenium(v) mono-oxo complexes electrochemically generated from trans-[RuIVLO(CI)]+(L = tmc or 15 -tmc; tmc = 1,4,8,11 -tetramethyI-1,4,8,11 -tetra-azacyclotetradecane, 15-tmc = 1,4,8,12-tetramethyl-1,4,8,12-tetraazacyclopentadecane) are active oxidative catalysts for the conversion of alcohol into aldehyde; X-ray analysis of trans-[RuIV(tmc)O(CI)]CIO4 yielded Ru=O 1.765(7) Å, and Ru-CI 2.505(3) Å.

AB - Ruthenium(v) mono-oxo complexes electrochemically generated from trans-[RuIVLO(CI)]+(L = tmc or 15 -tmc; tmc = 1,4,8,11 -tetramethyI-1,4,8,11 -tetra-azacyclotetradecane, 15-tmc = 1,4,8,12-tetramethyl-1,4,8,12-tetraazacyclopentadecane) are active oxidative catalysts for the conversion of alcohol into aldehyde; X-ray analysis of trans-[RuIV(tmc)O(CI)]CIO4 yielded Ru=O 1.765(7) Å, and Ru-CI 2.505(3) Å.

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DO - 10.1039/C39850000988

M3 - Journal article

SN - 0022-4936

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EP - 990

JO - Journal of the Chemical Society - Series Chemical Communications

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Che CM, Wong KY, Mak TCW. Oxo-ruthenium(V) complexes of macrocyclic tetradentate tertiary amines that function as active electrochemical oxidative catalysts, and X-ray crystal structure of trans-[Ru^IV(tmc)O(CI)]CIO₄(tmc = 1,4,8,11 -tetramethyl-1,4,8,1 I-tetra-azacyclotetradecane). Journal of the Chemical Society - Series Chemical Communications. 1985 Jan 1;(14):988-990. doi: 10.1039/C39850000988