Novel Zn(II) coordination polymer based on 1,2-bis(4-pyridyl)hydrazine - From two-dimensional to three-dimensional network

Huaishan Wang; Lap Szeto; Wesley Ting Kwok Chan; Ho Lun Yeung; Ka Leung Wong; Wing Tak Wong

doi:10.1139/v11-132

Novel Zn(II) coordination polymer based on 1,2-bis(4-pyridyl)hydrazine - From two-dimensional to three-dimensional network

Huaishan Wang, Lap Szeto, Wesley Ting Kwok Chan, Ho Lun Yeung, Ka Leung Wong, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

1 Citation (Scopus)

Abstract

Two MOFs were reported based on Zn(II) with 1,2-bis(4-pyridyl)hydrazine (L1); a two-dimensional interpenetrating MOF I of formula [Zn 2(L1) 2(L2) 2] ∞ was formed with terephthalic acid (L2) as an additional linker. A three-dimensional MOF II of formula [Zn 2(L1) 2(L3) 2] ∞, was formed with the use of a larger spacer 2,6-naphthalenedicarboxylic acid (L3). MOF II consists of large porosity with a total volume of 3746 Å 3 that occupies 34.1% of the unit cell.

Original language	English
Pages (from-to)	100-107
Number of pages	8
Journal	Canadian Journal of Chemistry
Volume	90
Issue number	1
DOIs	https://doi.org/10.1139/v11-132
Publication status	Published - 1 Jan 2012

Keywords

1,2-bis(4-pyridyl)hydrazine
Coordination polymer
Hydrogen bond
Interpenetrating polymer
Metal organic framework
Microporous

ASJC Scopus subject areas

Catalysis
General Chemistry
Organic Chemistry

More information

10.1139/v11-132

Cite this

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title = "Novel Zn(II) coordination polymer based on 1,2-bis(4-pyridyl)hydrazine - From two-dimensional to three-dimensional network",

abstract = "Two MOFs were reported based on Zn(II) with 1,2-bis(4-pyridyl)hydrazine (L1); a two-dimensional interpenetrating MOF I of formula [Zn 2(L1) 2(L2) 2] ∞ was formed with terephthalic acid (L2) as an additional linker. A three-dimensional MOF II of formula [Zn 2(L1) 2(L3) 2] ∞, was formed with the use of a larger spacer 2,6-naphthalenedicarboxylic acid (L3). MOF II consists of large porosity with a total volume of 3746 {\AA} 3 that occupies 34.1% of the unit cell.",

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author = "Huaishan Wang and Lap Szeto and Chan, {Wesley Ting Kwok} and Yeung, {Ho Lun} and Wong, {Ka Leung} and Wong, {Wing Tak}",

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AU - Wang, Huaishan

AU - Szeto, Lap

AU - Chan, Wesley Ting Kwok

AU - Yeung, Ho Lun

AU - Wong, Ka Leung

AU - Wong, Wing Tak

PY - 2012/1/1

Y1 - 2012/1/1

N2 - Two MOFs were reported based on Zn(II) with 1,2-bis(4-pyridyl)hydrazine (L1); a two-dimensional interpenetrating MOF I of formula [Zn 2(L1) 2(L2) 2] ∞ was formed with terephthalic acid (L2) as an additional linker. A three-dimensional MOF II of formula [Zn 2(L1) 2(L3) 2] ∞, was formed with the use of a larger spacer 2,6-naphthalenedicarboxylic acid (L3). MOF II consists of large porosity with a total volume of 3746 Å 3 that occupies 34.1% of the unit cell.

AB - Two MOFs were reported based on Zn(II) with 1,2-bis(4-pyridyl)hydrazine (L1); a two-dimensional interpenetrating MOF I of formula [Zn 2(L1) 2(L2) 2] ∞ was formed with terephthalic acid (L2) as an additional linker. A three-dimensional MOF II of formula [Zn 2(L1) 2(L3) 2] ∞, was formed with the use of a larger spacer 2,6-naphthalenedicarboxylic acid (L3). MOF II consists of large porosity with a total volume of 3746 Å 3 that occupies 34.1% of the unit cell.

KW - 1,2-bis(4-pyridyl)hydrazine

KW - Coordination polymer

KW - Hydrogen bond

KW - Interpenetrating polymer

KW - Metal organic framework

KW - Microporous

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U2 - 10.1139/v11-132

DO - 10.1139/v11-132

M3 - Journal article

SN - 0008-4042

VL - 90

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JO - Canadian Journal of Chemistry

JF - Canadian Journal of Chemistry

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Novel Zn(II) coordination polymer based on 1,2-bis(4-pyridyl)hydrazine - From two-dimensional to three-dimensional network

Abstract

Keywords

ASJC Scopus subject areas

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