Novel Zn(II) coordination polymer based on 1,2-bis(4-pyridyl)hydrazine - From two-dimensional to three-dimensional network

Huaishan Wang, Lap Szeto, Wesley Ting Kwok Chan, Ho Lun Yeung, Ka Leung Wong, Wing Tak Wong

Research output: Journal article publicationJournal articleAcademic researchpeer-review

1 Citation (Scopus)

Abstract

Two MOFs were reported based on Zn(II) with 1,2-bis(4-pyridyl)hydrazine (L1); a two-dimensional interpenetrating MOF I of formula [Zn 2(L1) 2(L2) 2] ∞ was formed with terephthalic acid (L2) as an additional linker. A three-dimensional MOF II of formula [Zn 2(L1) 2(L3) 2] ∞, was formed with the use of a larger spacer 2,6-naphthalenedicarboxylic acid (L3). MOF II consists of large porosity with a total volume of 3746 Å 3 that occupies 34.1% of the unit cell.
Original languageEnglish
Pages (from-to)100-107
Number of pages8
JournalCanadian Journal of Chemistry
Volume90
Issue number1
DOIs
Publication statusPublished - 1 Jan 2012

Keywords

  • 1,2-bis(4-pyridyl)hydrazine
  • Coordination polymer
  • Hydrogen bond
  • Interpenetrating polymer
  • Metal organic framework
  • Microporous

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Organic Chemistry

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