Novel fluorescent molecular clips: Selective recognition towards Fe 3+ in aqueous solution

Lin Li, Neng Fang She, Zhuan Fei, Pui Kin So, Yu Zhou Wang, Li Ping Cao, An Xin Wu, Zhongping Yao

Research output: Journal article publicationJournal articleAcademic researchpeer-review

13 Citations (Scopus)

Abstract

In this paper, we report the synthesis, characterization and Fe3+-sensing properties of a series of new artificial fluorescent molecular clips, and structure of clip 1 is confirmed by X-ray crystallography. All these molecular clips had the ability to bind and sense Fe3+selectively through decrease fluorescence responses in THF-MeOH-Water. Fluorimetric titration experiment indicated that the quenching of these compounds' fluorescence upon Fe3+probably arises from the electron/energy transfer between Fe3+and the excited chemosensors. The limit of detection, linear concentration range and selectivity of the fluorescent molecular clips were evaluated in this study as well.
Original languageEnglish
Pages (from-to)1103-1110
Number of pages8
JournalJournal of Fluorescence
Volume21
Issue number3
DOIs
Publication statusPublished - 1 May 2011

Keywords

  • Chemosensor
  • Diethoxycarbonyl glycoluril derivative
  • Fe 3+
  • Fluorescence quenching

ASJC Scopus subject areas

  • Spectroscopy
  • Biochemistry
  • Clinical Biochemistry

Cite this