Novel chiral aminophosphine ligand: Synthesis and application in asymmetric catalytic hydrogenation reaction

Yi Xin Chen; Yue Ming Li; Kim Hung Lam; Albert Sun Chi Chan

Novel chiral aminophosphine ligand: Synthesis and application in asymmetric catalytic hydrogenation reaction

Yi Xin Chen, Yue Ming Li, Kim Hung Lam, Albert Sun Chi Chan

Research output: Journal article publication › Journal article › Academic research › peer-review

Abstract

A new chiral aminophosphine ligand 6, 6′-dhnethoxy-2, 2′-bis (diphenylphosphinoamino) biphenyl (DMBDPPABP) was prepared and its rhodimn complex was found to be an effective catalyst for the asymmetric hydrogenation of amidoacrylic acid and its derivatives. The effects of solvent and reaction temperature on enantioselectivity were also studied.

Original language	English
Pages (from-to)	66-70
Number of pages	5
Journal	Chinese Journal of Chemistry
Volume	21
Issue number	1
Publication status	Published - 29 Aug 2003

Keywords

6,6-′-dimethoxy-2,2-′bis(diphenylphosphinoamino)biphenyl
Aminophosphine
Asymmetric hydrogenation
Chiral llgand

ASJC Scopus subject areas

General Chemistry

Cite this

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title = "Novel chiral aminophosphine ligand: Synthesis and application in asymmetric catalytic hydrogenation reaction",

abstract = "A new chiral aminophosphine ligand 6, 6′-dhnethoxy-2, 2′-bis (diphenylphosphinoamino) biphenyl (DMBDPPABP) was prepared and its rhodimn complex was found to be an effective catalyst for the asymmetric hydrogenation of amidoacrylic acid and its derivatives. The effects of solvent and reaction temperature on enantioselectivity were also studied.",

keywords = "6,6-′-dimethoxy-2,2-′bis(diphenylphosphinoamino)biphenyl, Aminophosphine, Asymmetric hydrogenation, Chiral llgand",

author = "Chen, {Yi Xin} and Li, {Yue Ming} and Lam, {Kim Hung} and Chan, {Albert Sun Chi}",

year = "2003",

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day = "29",

language = "English",

volume = "21",

pages = "66--70",

journal = "Chinese Journal of Chemistry",

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T1 - Novel chiral aminophosphine ligand

T2 - Synthesis and application in asymmetric catalytic hydrogenation reaction

AU - Chen, Yi Xin

AU - Li, Yue Ming

AU - Lam, Kim Hung

AU - Chan, Albert Sun Chi

PY - 2003/8/29

Y1 - 2003/8/29

N2 - A new chiral aminophosphine ligand 6, 6′-dhnethoxy-2, 2′-bis (diphenylphosphinoamino) biphenyl (DMBDPPABP) was prepared and its rhodimn complex was found to be an effective catalyst for the asymmetric hydrogenation of amidoacrylic acid and its derivatives. The effects of solvent and reaction temperature on enantioselectivity were also studied.

AB - A new chiral aminophosphine ligand 6, 6′-dhnethoxy-2, 2′-bis (diphenylphosphinoamino) biphenyl (DMBDPPABP) was prepared and its rhodimn complex was found to be an effective catalyst for the asymmetric hydrogenation of amidoacrylic acid and its derivatives. The effects of solvent and reaction temperature on enantioselectivity were also studied.

KW - 6,6-′-dimethoxy-2,2-′bis(diphenylphosphinoamino)biphenyl

KW - Aminophosphine

KW - Asymmetric hydrogenation

KW - Chiral llgand

UR - http://www.scopus.com/inward/record.url?scp=0041939826&partnerID=8YFLogxK

M3 - Journal article

AN - SCOPUS:0041939826

SN - 1001-604X

VL - 21

SP - 66

EP - 70

JO - Chinese Journal of Chemistry

JF - Chinese Journal of Chemistry

IS - 1

ER -

Novel chiral aminophosphine ligand: Synthesis and application in asymmetric catalytic hydrogenation reaction

Abstract

Keywords

ASJC Scopus subject areas

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