Novel chiral aminophosphine ligand: Synthesis and application in asymmetric catalytic hydrogenation reaction

Yi Xin Chen, Yue Ming Li, Kim Hung Lam, Albert Sun Chi Chan

Research output: Journal article publicationJournal articleAcademic researchpeer-review

7 Citations (Scopus)

Abstract

A new chiral aminophosphine ligand 6, 6′-dhnethoxy-2, 2′-bis (diphenylphosphinoamino) biphenyl (DMBDPPABP) was prepared and its rhodimn complex was found to be an effective catalyst for the asymmetric hydrogenation of amidoacrylic acid and its derivatives. The effects of solvent and reaction temperature on enantioselectivity were also studied.

Original languageEnglish
Pages (from-to)66-70
Number of pages5
JournalChinese Journal of Chemistry
Volume21
Issue number1
Publication statusPublished - 29 Aug 2003

Keywords

  • 6,6-′-dimethoxy-2,2-′bis(diphenylphosphinoamino)biphenyl
  • Aminophosphine
  • Asymmetric hydrogenation
  • Chiral llgand

ASJC Scopus subject areas

  • Chemistry(all)

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