Novel μ5-coordination modes of aryl and alkyl ethynides and classification of metal-ligand interactions in silver(I) complexes

Liang Zhao; Wai Yeung Wong; Thomas C.W. Mak

doi:10.1002/chem.200501449

Novel μ₅-coordination modes of aryl and alkyl ethynides and classification of metal-ligand interactions in silver(I) complexes

Liang Zhao, Wai Yeung Wong, Thomas C.W. Mak

Research output: Journal article publication › Journal article › Academic research › peer-review

64 Citations (Scopus)

Abstract

Novel μ5-η1,η1, η1,η1,η2 and μ5- η1,η1,η1,η2, η2 coordination modes of alkyl and aryl ethynide moieties are found in silver(I) complexes 1-5, and the metal-ligand distances can be classified into σ, π and mixed (σ,π) types. With the consistent square-pyramidal capping Ag5 baskets of the ethynide moiety as supramolecular synthons, a series of two- and three-dimensional coordination networks are obtained. KGaA.

Original language	English
Pages (from-to)	4865-4872
Number of pages	8
Journal	Chemistry - A European Journal
Volume	12
Issue number	18
DOIs	https://doi.org/10.1002/chem.200501449
Publication status	Published - 14 Jun 2006
Externally published	Yes

Keywords

Argentophilicity
Coordination modes
Coordination polymers
Metal-ligand interactions
Silver complexes

ASJC Scopus subject areas

General Chemistry

More information

10.1002/chem.200501449

Cite this

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title = "Novel μ5-coordination modes of aryl and alkyl ethynides and classification of metal-ligand interactions in silver(I) complexes",

abstract = "Novel μ5-η1,η1, η1,η1,η2 and μ5- η1,η1,η1,η2, η2 coordination modes of alkyl and aryl ethynide moieties are found in silver(I) complexes 1-5, and the metal-ligand distances can be classified into σ, π and mixed (σ,π) types. With the consistent square-pyramidal capping Ag5 baskets of the ethynide moiety as supramolecular synthons, a series of two- and three-dimensional coordination networks are obtained. KGaA.",

keywords = "Argentophilicity, Coordination modes, Coordination polymers, Metal-ligand interactions, Silver complexes",

author = "Liang Zhao and Wong, {Wai Yeung} and Mak, {Thomas C.W.}",

year = "2006",

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language = "English",

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journal = "Chemistry - A European Journal",

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T1 - Novel μ5-coordination modes of aryl and alkyl ethynides and classification of metal-ligand interactions in silver(I) complexes

AU - Zhao, Liang

AU - Wong, Wai Yeung

AU - Mak, Thomas C.W.

PY - 2006/6/14

Y1 - 2006/6/14

N2 - Novel μ5-η1,η1, η1,η1,η2 and μ5- η1,η1,η1,η2, η2 coordination modes of alkyl and aryl ethynide moieties are found in silver(I) complexes 1-5, and the metal-ligand distances can be classified into σ, π and mixed (σ,π) types. With the consistent square-pyramidal capping Ag5 baskets of the ethynide moiety as supramolecular synthons, a series of two- and three-dimensional coordination networks are obtained. KGaA.

AB - Novel μ5-η1,η1, η1,η1,η2 and μ5- η1,η1,η1,η2, η2 coordination modes of alkyl and aryl ethynide moieties are found in silver(I) complexes 1-5, and the metal-ligand distances can be classified into σ, π and mixed (σ,π) types. With the consistent square-pyramidal capping Ag5 baskets of the ethynide moiety as supramolecular synthons, a series of two- and three-dimensional coordination networks are obtained. KGaA.

KW - Argentophilicity

KW - Coordination modes

KW - Coordination polymers

KW - Metal-ligand interactions

KW - Silver complexes

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DO - 10.1002/chem.200501449

M3 - Journal article

SN - 0947-6539

VL - 12

SP - 4865

EP - 4872

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 18

ER -