Non-equilibrium insertion of lithium ions into graphite

Na Li, Ming Zi Sun, Sooyeon Hwang, Shuang Li, Hong Yang Zhao, Ya Ping Du, Bo Long Huang, Dong Su

Research output: Journal article publicationJournal articleAcademic researchpeer-review

5 Citations (Scopus)


Graphite has been regarded as the most important anode material for currently used lithium-ion batteries due to its two-dimensional (2D) nature hosting ionic intercalations. However, the kinetic insertion of Li ions is still not well known microscopically. In this work, we investigate the real-time intercalation process of Li ions using in situ transmission electron microscopy. We observe the lithium insertion process at the atomic scale, in which the graphite layers undergo expansion, forming wrinkles and finally inhomogeneous cracks as the Li ions accumulate, different from the proposed models. Leveraging on theoretical simulations, Li-ion migration driven by an external electrical field is suggested to be induced into the irreversible wrinkled structures. This non-equilibrium behavior that occur in lithium-ion batteries can be more pronounced at a high charging rate, which will practically degrade the capacity of graphite. This work unveils the reaction scenario of the non-equilibrium Li-ion insertion, which benefits the understanding of the performance of graphite-based energy-storage devices.

Original languageEnglish
Pages (from-to)12080-12086
Number of pages7
JournalJournal of Materials Chemistry A
Issue number20
Publication statusPublished - 28 May 2021

ASJC Scopus subject areas

  • Chemistry(all)
  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

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