New tricyanoiron(III) building blocks for the construction of molecule-based magnets

Wai Lun Man; Jing Xiang; Pui Ha Lau; Song Gao; Wing Tak Wong; Tai Chu Lau

doi:10.1007/s11426-010-4119-4

New tricyanoiron(III) building blocks for the construction of molecule-based magnets

Wai Lun Man, Jing Xiang, Pui Ha Lau, Song Gao, Wing Tak Wong, Tai Chu Lau

Research output: Journal article publication › Journal article › Academic research › peer-review

2 Citations (Scopus)

Abstract

A series of tricyanoiron(III) complexes with the general formula mer-[FeIII(5-Xsap)(CN)3]2-(X = H, Me, MeO, Cl or Br, sapH2= N-salicylidene-o-aminophenol) have been synthesized. These complexes were characterized by IR, ESI-MS, UV/Vis, elemental analysis and magnetic measurements. The structures of (PPh4)2[FeIII(sap)(CN)3] and (PPh4)2[FeIII(5-Mesap)(CN)3] have been determined by X-ray crystallography. These low-spin d5tricyanoiron(III) complexes are potential building blocks for the construction of molecule-based magnets.

Original language	English
Pages (from-to)	2106-2111
Number of pages	6
Journal	Science China Chemistry
Volume	53
Issue number	10
DOIs	https://doi.org/10.1007/s11426-010-4119-4
Publication status	Published - 1 Oct 2010
Externally published	Yes

Keywords

building block
cyano
iron
molecule-based magnet
Schiff base

ASJC Scopus subject areas

General Chemistry

More information

10.1007/s11426-010-4119-4

Cite this

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title = "New tricyanoiron(III) building blocks for the construction of molecule-based magnets",

abstract = "A series of tricyanoiron(III) complexes with the general formula mer-[FeIII(5-Xsap)(CN)3]2-(X = H, Me, MeO, Cl or Br, sapH2= N-salicylidene-o-aminophenol) have been synthesized. These complexes were characterized by IR, ESI-MS, UV/Vis, elemental analysis and magnetic measurements. The structures of (PPh4)2[FeIII(sap)(CN)3] and (PPh4)2[FeIII(5-Mesap)(CN)3] have been determined by X-ray crystallography. These low-spin d5tricyanoiron(III) complexes are potential building blocks for the construction of molecule-based magnets.",

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T1 - New tricyanoiron(III) building blocks for the construction of molecule-based magnets

AU - Man, Wai Lun

AU - Xiang, Jing

AU - Lau, Pui Ha

AU - Gao, Song

AU - Wong, Wing Tak

AU - Lau, Tai Chu

PY - 2010/10/1

Y1 - 2010/10/1

N2 - A series of tricyanoiron(III) complexes with the general formula mer-[FeIII(5-Xsap)(CN)3]2-(X = H, Me, MeO, Cl or Br, sapH2= N-salicylidene-o-aminophenol) have been synthesized. These complexes were characterized by IR, ESI-MS, UV/Vis, elemental analysis and magnetic measurements. The structures of (PPh4)2[FeIII(sap)(CN)3] and (PPh4)2[FeIII(5-Mesap)(CN)3] have been determined by X-ray crystallography. These low-spin d5tricyanoiron(III) complexes are potential building blocks for the construction of molecule-based magnets.

AB - A series of tricyanoiron(III) complexes with the general formula mer-[FeIII(5-Xsap)(CN)3]2-(X = H, Me, MeO, Cl or Br, sapH2= N-salicylidene-o-aminophenol) have been synthesized. These complexes were characterized by IR, ESI-MS, UV/Vis, elemental analysis and magnetic measurements. The structures of (PPh4)2[FeIII(sap)(CN)3] and (PPh4)2[FeIII(5-Mesap)(CN)3] have been determined by X-ray crystallography. These low-spin d5tricyanoiron(III) complexes are potential building blocks for the construction of molecule-based magnets.

KW - building block

KW - cyano

KW - iron

KW - molecule-based magnet

KW - Schiff base

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U2 - 10.1007/s11426-010-4119-4

DO - 10.1007/s11426-010-4119-4

M3 - Journal article

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SP - 2106

EP - 2111

JO - Science China Chemistry

JF - Science China Chemistry

IS - 10

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New tricyanoiron(III) building blocks for the construction of molecule-based magnets

Abstract

Keywords

ASJC Scopus subject areas

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