New insights into creep characteristics of calcium silicate hydrates at molecular level

MF Kai, LW Zhang, KM Liew

Research output: Journal article publicationJournal articleAcademic researchpeer-review

3 Citations (Scopus)

Abstract

The fundamental mechanisms under concrete creep are far from being fully understood, especially at the molecular level. Hereby, a calcium-silicate-hydrate (C-S-H) molecular model is developed to explain, for the first time, the creep characteristics at various stress states, temperature levels and water contents, which are not accessible experimentally. Rather tensile and compressive loadings, C-S-H only creeps under shear loadings originating from the sliding of the calcium silicate layers over each other as the interlayer component (water and ions) acts as a lubricator. A heterogeneous creep characteristic is observed. Elevated temperature reduces the interlayer lubricator viscosity and weakens the interfacial adhesion between the layers and the interlayer lubricator, which accelerates C-S-H creep. The removal of interlayer water enhances the creep resistance, resulting from the reduced interlayer space and enhanced interfacial adhesion. The atomic-level mechanisms explain the inter-CSH-particle behaviours at the microscale, which bridges the gap between atomistic simulation and microcosmic phenomenon.

Original languageEnglish
Article number106366
JournalCement and Concrete Research
Volume142
DOIs
Publication statusPublished - Apr 2021
Externally publishedYes

Keywords

  • Atomistic simulation
  • B. Calcium-silicate-hydrate (C-S-H)
  • C. Creep
  • Temperature
  • Water content

ASJC Scopus subject areas

  • Building and Construction
  • Materials Science(all)

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