Abstract
Two new solution-processible platinum(II) polyyne polymers P1 and P2 bridged by diketopyrrolopyrrole and isoindigo units have been synthesized via the CuI-catalyzed dehydrohalogenation reaction of the platinum(II) chloride precursors and the corresponding diacetylene ligands. The photophysical and electrochemical properties of P1 and P2 were investigated. These metallo-organic polymers have relatively narrow bandgaps of around 1.58–1.70 eV and broad absorption bands which are favorable for harvesting solar energy.
| Original language | English |
|---|---|
| Pages (from-to) | 159-168 |
| Number of pages | 10 |
| Journal | Journal of Inorganic and Organometallic Polymers and Materials |
| Volume | 25 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 1 Jan 2015 |
| Externally published | Yes |
Keywords
- Acetylide
- Bandgap
- Diketopyrrolopyrrole
- Isoindigo
- Platinum
ASJC Scopus subject areas
- Polymers and Plastics
- Materials Chemistry
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