Narrow Bandgap Platinum(II)-Containing Polyynes with Diketopyrrolopyrrole and Isoindigo Spacers

Qian Liu, Cheuk Lam Ho, Yih Hsing Lo, Hua Li, Wai Yeung Wong

Research output: Journal article publicationJournal articleAcademic researchpeer-review

11 Citations (Scopus)

Abstract

Two new solution-processible platinum(II) polyyne polymers P1 and P2 bridged by diketopyrrolopyrrole and isoindigo units have been synthesized via the CuI-catalyzed dehydrohalogenation reaction of the platinum(II) chloride precursors and the corresponding diacetylene ligands. The photophysical and electrochemical properties of P1 and P2 were investigated. These metallo-organic polymers have relatively narrow bandgaps of around 1.58–1.70 eV and broad absorption bands which are favorable for harvesting solar energy.
Original languageEnglish
Pages (from-to)159-168
Number of pages10
JournalJournal of Inorganic and Organometallic Polymers and Materials
Volume25
Issue number1
DOIs
Publication statusPublished - 1 Jan 2015
Externally publishedYes

Keywords

  • Acetylide
  • Bandgap
  • Diketopyrrolopyrrole
  • Isoindigo
  • Platinum

ASJC Scopus subject areas

  • Polymers and Plastics
  • Materials Chemistry

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