Multiple bismuth(III)-thioether secondary interactions integrate metalloporphyrin ligands into functional networks

Kunhao Li, Guo Huang, Zhengtao Xu, Mingliang Zhang, Matthias Zeller, Allen D. Hunter, Stephen Sin Yin Chui, Chi Ming Che, Wai Yeung Wong

Research output: Journal article publicationJournal articleAcademic researchpeer-review

10 Citations (Scopus)

Abstract

We introduce the 1,2,3-tris(organylthiophenyl) group as a symmetrical, multidentate chelation link for building coordination networks. For this, zinc(II) 5,10,15,20-tetrakis[3′,4′,5′-tris(methylthio)phenyl] porphyrin was synthesized and integrated into a two-dimensional network via coordination with BiBr3. The coordination link exhibits an unusually complex bonding pattern, involving six S atoms from two neighboring ligands that form multiple Bi-S interactions (distances ranging from 3.08 to 3.63 Å) with a dimerlike unit of Bi2Br6. The electronic interaction between the porphyrin center and the Bi2Br6block was illustrated by the diffuse-reflectance spectrum of the network compound, in which a modest red-shifted feature at 1.8 eV was seen (while the Q-band absorption of the metalloporphyrin core continues to be dominant at 1.9 eV).
Original languageEnglish
Pages (from-to)4844-4849
Number of pages6
JournalInorganic Chemistry
Volume46
Issue number12
DOIs
Publication statusPublished - 11 Jun 2007
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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