Multi-color electrochromism from coordination nanosheets based on a terpyridine-Fe(ii) complex

Yu Kuai, Weijun Li, Yujie Dong, Wai Yeung Wong, Shuanma Yan, Yuyu Dai, Cheng Zhang

Research output: Journal article publicationJournal articleAcademic researchpeer-review

12 Citations (Scopus)

Abstract

A metal complex nanosheet was synthesized by the liquid-liquid interface self-assembly method from a star-shaped ligand of tris[4-(4′-2,2′:6′,2′′-terpyridyl)-phenyl]amine in organic solvents and metal ion Fe(ii) in water solution. The as-prepared nanosheet possessed excessively smooth morphology with a thickness of hundreds of nanometers. Adhering to an ITO glass, the nanosheet showed noticeable electrochromism from purplish red at 0 V to orange-yellow at 1.4 V and green at 1.6 V. Besides, the nanosheet exhibited outstanding stability with the optical contrast maintained at almost 100% of its original electrochemical activity over 500 cycles. The liquid-liquid interface self-assembly method was proven to be promising to prepare a polymeric metal complex for potential electrochromic applications.

Original languageEnglish
Pages (from-to)15121-15126
Number of pages6
JournalDalton Transactions
Volume48
Issue number40
DOIs
Publication statusPublished - Sep 2019

ASJC Scopus subject areas

  • Inorganic Chemistry

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