Microstructural effects on macroscale thermal properties in nanofluids

The recent first-principle model shows that heat conduction in nanofluids can be diffusion-dominant or thermal-wave-dominant depending on their microscale physics (structures, properties and activities). As the first attempt of quantifying when and to what extent thermal waves become important, we numerically examine effects of particlefluid conductivity ratio, particle shape, volume fraction and nondimensional particlefluid interfacial area in the unit-cell on macroscale thermal properties for nanofluids consisting of in-line arrays of perfectly dispersed two-dimensional circular, square and hollow particles, respectively. In simple and perfectly dispersed nanofluids, the heat conduction is diffusion-dominant so the effective thermal conductivity can be predicted adequately by the mixture rule with the effect of particle shape and particlefluid conductivity ratio incorporated into its empirical parameter. Thermal waves appear more likely at smaller particlefluid conductivity ratio (< 1) and lower particle-volume-fraction, which agrees with the experimentally observed significant conductivity enhancement in the oil-in-water emulsion. The computed thermal conductivity predicts some experimental data in the literature very well and shows the sensitivity to the nondimensional particlefluid interfacial area in the unit-cell.