Microanalysis of dust deposition inside Emperor Qin's Terra-cotta warriors and Horses Museum

Tafeng Hu, Junji Cao, Shuncheng Lee, Xuxiang Li, Zhenxing Shen, Bo Rong, Zhisheng An

Research output: Journal article publicationJournal articleAcademic researchpeer-review

3 Citations (Scopus)

Abstract

Indoor dust deposition, including long-term (>10 years) deposition, short-term (∼0.5 year) deposition, and pigment flake samples from partially restored warriors were collected in Emperor Qin's Terra-cotta Warriors and Horses Museum in Xi'an, Shaanxi Province, China. Morphological and elemental analyses of individual particles were performed with scanning electron microscopy and energy dispersive X-ray spectrometry to investigate their composition and potential to damage the statues. Most of the indoor dust was composed of clay minerals, fly ash, and biogenic particles. Particles in 51.5% of the short-term deposition, and 49.5% of the long-term deposition contained elemental sulfur. Particles which contained sulfur were mostly associated with calcium sulfate in an internally mixed state with clay or quartz. Crystals of calcium sulfate were also found near interconnected pits and cracks on the outer surface of pigment flakes, revealing an acidic chemical reaction between sulfur dioxide and pigment material or deposited particles as the cause of pits and cracks on the statues' faces.
Original languageEnglish
Pages (from-to)59-66
Number of pages8
JournalAerosol and Air Quality Research
Volume10
Issue number1
DOIs
Publication statusPublished - 1 Feb 2010

Keywords

  • Dust deposition
  • Museum
  • Scanning electron microscopy
  • Terra-cotta warriors

ASJC Scopus subject areas

  • Environmental Chemistry
  • Pollution

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