TY - JOUR
T1 - Microalgae-derived single-atom oxygen reduction catalysts for zinc-air batteries
AU - Ma, Linlin
AU - Hu, Xiao
AU - Min, Yuan
AU - Zhang, Xinyu
AU - Liu, Wujun
AU - Lam, Paul Kwan Sing
AU - Li, Molly Meng Jung
AU - Zeng, Raymond Jianxiong
AU - Ye, Ruquan
N1 - Funding Information:
The authors thank the funding support from the National Natural Science Foundation of China (21905240, 21976170, 21590812, U20A20235 and 51821006), the International Partnership Program of Chinese Academy of Sciences (GJHZ1845), the Program for Changjiang Scholars and Innovative Research Team in University of the Ministry of Education of China. R.Y. acknowledges the support from CityU Applied Research Grant (9667224), Chow Sang Sang Group Research Fund (9229060), State Key Laboratory of Marine Pollution (SKLMP/IRF/0029) and the Science, Technology and Innovation Commission of Shenzhen under Shenzhen Virtual University Park Special Fund (2021Szvup129). The authors thank Professor Wen-Wei Li from University of Science and Technology of China for his helpful discussion and suggestion.
Funding Information:
The authors thank the funding support from the National Natural Science Foundation of China ( 21905240 , 21976170 , 21590812 , U20A20235 and 51821006 ), the International Partnership Program of Chinese Academy of Sciences ( GJHZ1845 ), the Program for Changjiang Scholars and Innovative Research Team in University of the Ministry of Education of China . R.Y. acknowledges the support from CityU Applied Research Grant ( 9667224 ), Chow Sang Sang Group Research Fund ( 9229060 ), State Key Laboratory of Marine Pollution ( SKLMP/IRF/0029 ) and the Science, Technology and Innovation Commission of Shenzhen under Shenzhen Virtual University Park Special Fund ( 2021Szvup129 ). The authors thank Professor Wen-Wei Li from University of Science and Technology of China for his helpful discussion and suggestion.
Publisher Copyright:
© 2022 Elsevier Ltd
PY - 2023/1/25
Y1 - 2023/1/25
N2 - The need to fight against global warming has motivated the development of new technologies for green production of various chemicals and materials. Microalgae can convert CO2 into valuable biofuels, thus playing important roles in carbon neutrality. However, appropriately utilization of microalgae biomass remains an important issue to address. Here we demonstrate that the microalgae biomass with abundant membrane-bound biomolecules and singly isolated metal atoms can be upgraded into single-atom site catalysts (SACs) with high oxygen reduction reaction (ORR) activity. Through hydrothermal and pyrolysis treatment of microalgae, Fe–N4 structured SACs (malg-SACs) are obtained, as confirmed by near edge X-ray absorption fine structure (NEXAFS), X-ray absorption near-edge structure (XANES), and extended X-ray absorption fine structure (EXAFS). Under optimal conditions, the malg-SAC exhibits a remarkable ORR activity (E1/2 = 0.875 V vs. RHE), outstanding long-term stability, and good resistance to CO and CH3OH poisoning. When assembled in a primary zinc-air battery, the full device reaches a maximum power density of 220.7 mW cm−2 with negligible voltage decay over the 6 h test, far outperforming the commercial Pt/C (112.1 mW cm−2). Our work reports a sustainable pathway to convert CO2-capture biomass into high-performance SACs, simultaneously addressing environmental and energy issues.
AB - The need to fight against global warming has motivated the development of new technologies for green production of various chemicals and materials. Microalgae can convert CO2 into valuable biofuels, thus playing important roles in carbon neutrality. However, appropriately utilization of microalgae biomass remains an important issue to address. Here we demonstrate that the microalgae biomass with abundant membrane-bound biomolecules and singly isolated metal atoms can be upgraded into single-atom site catalysts (SACs) with high oxygen reduction reaction (ORR) activity. Through hydrothermal and pyrolysis treatment of microalgae, Fe–N4 structured SACs (malg-SACs) are obtained, as confirmed by near edge X-ray absorption fine structure (NEXAFS), X-ray absorption near-edge structure (XANES), and extended X-ray absorption fine structure (EXAFS). Under optimal conditions, the malg-SAC exhibits a remarkable ORR activity (E1/2 = 0.875 V vs. RHE), outstanding long-term stability, and good resistance to CO and CH3OH poisoning. When assembled in a primary zinc-air battery, the full device reaches a maximum power density of 220.7 mW cm−2 with negligible voltage decay over the 6 h test, far outperforming the commercial Pt/C (112.1 mW cm−2). Our work reports a sustainable pathway to convert CO2-capture biomass into high-performance SACs, simultaneously addressing environmental and energy issues.
KW - Biomass upgrading
KW - Fe single atoms
KW - Oxygen reduction reaction
KW - Primary Zn-air battery
UR - https://www.scopus.com/pages/publications/85144294058
U2 - 10.1016/j.carbon.2022.12.039
DO - 10.1016/j.carbon.2022.12.039
M3 - Journal article
AN - SCOPUS:85144294058
SN - 0008-6223
VL - 203
SP - 827
EP - 834
JO - Carbon
JF - Carbon
ER -