Abstract
Ferromagnetic (L10phase) CoPt alloy nanoparticles (NPs) with extremely high magnetocrystalline anisotropy are promising candidates for the next generation of ultrahigh-density data storage systems. It is a challenge to generate L10CoPt NPs with high coercivity, controllable size, and a narrow size distribution. We report here the fabrication of L10CoPt NPs by employing a heterobimetallic CoPt-containing polymer as a single-source precursor. The average size of the resulting L10CoPt NPs is 3.4 nm with a reasonably narrow size standard deviation of 0.58 nm. The coercivity of L10CoPt NPs is 0.54 T which is suitable for practical application. We also fabricated the L10CoPt NP-based nanoline and nanodot arrays through nanoimprinting the polymer blend of CoPt-containing metallopolymer and polystyrene followed by pyrolysis. The successful transfer of the pre-defined patterns of the stamps onto the surface of the polymer blend implies that this material holds great application potential as a data storage medium.
Original language | English |
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Pages (from-to) | 7068-7074 |
Number of pages | 7 |
Journal | Nanoscale |
Volume | 8 |
Issue number | 13 |
DOIs | |
Publication status | Published - 7 Apr 2016 |
ASJC Scopus subject areas
- General Materials Science