Abstract
Reaction of N-(p-methoxybenzoyl)-S-benzoylsulphenamide1 with [Os3(CO)10(MeCN)2] at room temperature gives Os3(CO)10(μ3-S)]2 and [Os6(CO)20(μ4-S)(MeCN)]3 in moderate yield. The crystal structure of 3 has been determined. Complex 2 is an intermediate in the formation of 3. Complex 3 undergoes dissociation of CO to give [Os6(CO)19(μ3-S)] and [Os5(CO)15(μ4-S)].
Original language | English |
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Journal | Journal of Organometallic Chemistry |
Volume | 503 |
Issue number | 1 |
DOIs | |
Publication status | Published - 1 Nov 1995 |
Externally published | Yes |
Keywords
- Carbonyl
- Cluster
- Crystal structure
- Desulfurization
- Osmium
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
- Materials Chemistry