Lithiation-induced amorphization of Pd3P2S8 for highly efficient hydrogen evolution

Xiao Zhang, Zhimin Luo, Peng Yu, Yongqing Cai, Yonghua Du, Daoxiong Wu, Si Gao, Chaoliang Tan, Zhong Li, Minqin Ren, Thomas Osipowicz, Shuangming Chen, Zheng Jiang, Jiong Li, Ying Huang, Jian Yang, Ye Chen, Chung Yen Ang, Yanli Zhao, Peng WangLi Song, Xiaojun Wu, Zheng Liu, Armando Borgna, Hua Zhang

Research output: Journal article publicationJournal articleAcademic researchpeer-review

138 Citations (Scopus)

Abstract

Engineering material structures at the atomic level is a promising way to tune the physicochemical properties of materials and optimize their performance in various potential applications. Here, we show that the lithiation-induced amorphization of layered crystalline Pd3P2S8 activates this otherwise electrochemically inert material as a highly efficient hydrogen evolution catalyst. Electrochemical lithiation of the layered Pd3P2S8 crystal results in the formation of amorphous lithium-incorporated palladium phosphosulfide nanodots with abundant vacancies. The structure change during the lithiation-induced amorphization process is investigated in detail. The amorphous lithium-incorporated palladium phosphosulfide nanodots exhibit excellent electrocatalytic activity towards the hydrogen evolution reaction with an onset potential of -52 mV, a Tafel slope of 29 mV dec-1 and outstanding long-term stability. Experimental and theoretical investigations reveal that the tuning of morphology and structure of Pd3P2S8 (for example, dimension decrease, crystallinity loss, vacancy formation and lithium incorporation) contribute to the activation of its intrinsically inert electrocatalytic property. This work provides a unique way for structure tuning of a material to effectively manipulate its catalytic properties and functionalities.

Original languageEnglish
Pages (from-to)460-468
Number of pages9
JournalNature Catalysis
Volume1
Issue number6
DOIs
Publication statusPublished - 1 Jun 2018
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Bioengineering
  • Biochemistry
  • Process Chemistry and Technology

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