Laser spectroscopy of the A2Π-X2Σ system of TiN

T. W. Wong; Kam Wah Mok; N. S.K. Sze; A. S.C. Cheung

doi:10.1016/0022-4073(93)90038-J

Laser spectroscopy of the A²Π-X²Σ system of TiN

T. W. Wong, Kam Wah Mok, N. S.K. Sze, A. S.C. Cheung

Research output: Journal article publication › Journal article › Academic research › peer-review

6 Citations (Scopus)

Abstract

Five bandhead positions of the A2Π-X2Σ system of TiN between 6146 and 6236 Å have been studied using resolved laser induced fluorescence spectroscopy. ΔV=0 and ±1 transitions have been observed. The ground-state vibrational frequency has been measured to be 1039.8 cm-1, which is in excellent agreement with values obtained by Douglas and Veillette previously. The molecular constants obtained have been used to construct the potential energy curves for the A2Π and X2Σ states from which the Franck-Condon factors were also calculated.

Original language	English
Pages (from-to)	455-461
Number of pages	7
Journal	Journal of Quantitative Spectroscopy and Radiative Transfer
Volume	50
Issue number	5
DOIs	https://doi.org/10.1016/0022-4073(93)90038-J
Publication status	Published - 1 Jan 1993
Externally published	Yes

ASJC Scopus subject areas

Radiation
Atomic and Molecular Physics, and Optics
Spectroscopy

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10.1016/0022-4073(93)90038-J

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title = "Laser spectroscopy of the A2Π-X2Σ system of TiN",

abstract = "Five bandhead positions of the A2Π-X2Σ system of TiN between 6146 and 6236 {\AA} have been studied using resolved laser induced fluorescence spectroscopy. ΔV=0 and ±1 transitions have been observed. The ground-state vibrational frequency has been measured to be 1039.8 cm-1, which is in excellent agreement with values obtained by Douglas and Veillette previously. The molecular constants obtained have been used to construct the potential energy curves for the A2Π and X2Σ states from which the Franck-Condon factors were also calculated.",

author = "Wong, {T. W.} and Mok, {Kam Wah} and Sze, {N. S.K.} and Cheung, {A. S.C.}",

year = "1993",

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T1 - Laser spectroscopy of the A2Π-X2Σ system of TiN

AU - Wong, T. W.

AU - Mok, Kam Wah

AU - Sze, N. S.K.

AU - Cheung, A. S.C.

PY - 1993/1/1

Y1 - 1993/1/1

N2 - Five bandhead positions of the A2Π-X2Σ system of TiN between 6146 and 6236 Å have been studied using resolved laser induced fluorescence spectroscopy. ΔV=0 and ±1 transitions have been observed. The ground-state vibrational frequency has been measured to be 1039.8 cm-1, which is in excellent agreement with values obtained by Douglas and Veillette previously. The molecular constants obtained have been used to construct the potential energy curves for the A2Π and X2Σ states from which the Franck-Condon factors were also calculated.

AB - Five bandhead positions of the A2Π-X2Σ system of TiN between 6146 and 6236 Å have been studied using resolved laser induced fluorescence spectroscopy. ΔV=0 and ±1 transitions have been observed. The ground-state vibrational frequency has been measured to be 1039.8 cm-1, which is in excellent agreement with values obtained by Douglas and Veillette previously. The molecular constants obtained have been used to construct the potential energy curves for the A2Π and X2Σ states from which the Franck-Condon factors were also calculated.

UR - http://www.scopus.com/inward/record.url?scp=0010715731&partnerID=8YFLogxK

U2 - 10.1016/0022-4073(93)90038-J

DO - 10.1016/0022-4073(93)90038-J

M3 - Journal article

SN - 0022-4073

VL - 50

SP - 455

EP - 461

JO - Journal of Quantitative Spectroscopy and Radiative Transfer

JF - Journal of Quantitative Spectroscopy and Radiative Transfer

IS - 5

ER -

Laser spectroscopy of the A²Π-X²Σ system of TiN

Abstract

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