Lanthanide supramolecular helical diastereoselective breaking induced by point chirality: Mixture or P-helix, M-helix

Chi Tung Yeung, Wesley Ting Kwok Chan, Siu Cheong Yan, Kwan Leung Yu, King Him Yim, Wing Tak Wong, Ga Lai Law

Research output: Journal article publicationJournal articleAcademic researchpeer-review

34 Citations (Scopus)

Abstract

The self-assembly of lanthanide (europium or lanthanium) bimetallic triple helicates from two closely related chiral ligands resulted in a very different supramolecular phenomenon. One gave rise to significantly diastereoselective formation of a triple helicate, whereas the other led to diastereoselective breaking to generate a mixture of P and M diastereomers in ∼1 : 1.1 ratio. The first X-ray crystal structure of a chiral ligand based lanthanide triple-helicate indicates that successive CH-π interactions were found to maintain the supramolecular helical structure. This journal is
Original languageEnglish
Pages (from-to)592-595
Number of pages4
JournalChemical Communications
Volume51
Issue number3
DOIs
Publication statusPublished - 11 Jan 2015

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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