Kauzmann paradox: A possible crossover due to diminishing local excitations

Xinyuan GAO , Chin Yuan ONG, Chun Shing Lee, Cho Tung Yip, Hai Yao Deng, Chi Hang Lam

Research output: Journal article publicationJournal articleAcademic researchpeer-review

6 Citations (Scopus)

Abstract

The configurational entropy of supercooled liquids extrapolates to zero at the Kauzmann temperature, causing a crisis called the Kauzmann paradox. Here, using a class of multicomponent lattice glass models, we study a resolution of the paradox characterized by a sudden but smooth turn in the entropy as temperature goes sufficiently low. A scalar variant of the models reproduces the Kauzmann paradox with thermodynamic properties at very low temperatures dominated by correlations. An exactly solvable vector variant without correlation illustrates that a sudden entropy turn occurs when discrete local excitations are largely suppressed. Despite being disordered and infinitely degenerate, the ground states have zero entropy per particle.

Original languageEnglish
Article number174206
JournalPhysical Review B
Volume107
Issue number17
DOIs
Publication statusPublished - 1 May 2023

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics

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