Abstract
The configurational entropy of supercooled liquids extrapolates to zero at the Kauzmann temperature, causing a crisis called the Kauzmann paradox. Here, using a class of multicomponent lattice glass models, we study a resolution of the paradox characterized by a sudden but smooth turn in the entropy as temperature goes sufficiently low. A scalar variant of the models reproduces the Kauzmann paradox with thermodynamic properties at very low temperatures dominated by correlations. An exactly solvable vector variant without correlation illustrates that a sudden entropy turn occurs when discrete local excitations are largely suppressed. Despite being disordered and infinitely degenerate, the ground states have zero entropy per particle.
Original language | English |
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Article number | 174206 |
Journal | Physical Review B |
Volume | 107 |
Issue number | 17 |
DOIs | |
Publication status | Published - 1 May 2023 |
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Condensed Matter Physics