Isolation, characterisation, and crystal and molecular structure of [Os6AuC(CO)20(μ-OMe)]

Caroline M. Hay; Brian F.G. Johnson; Jack Lewis; Neville D. Prior; Paul R. Raithby; Wing Tak Wong

doi:10.1016/0022-328X(91)86216-D

Isolation, characterisation, and crystal and molecular structure of [Os₆AuC(CO)₂₀(μ-OMe)]

Caroline M. Hay, Brian F.G. Johnson, Jack Lewis, Neville D. Prior, Paul R. Raithby, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

7 Citations (Scopus)

Abstract

Treatment of [Os3(CO)10(μ-AuPEt3)(μ-COMe)] with [Os3(CO)10(NCMe)2] in refluxing toluene affords the new carbido compound [Os6AuC(CO)20(μ-OMe)] (1). A single-crystal X-ray structure analysis of 1 shows that an Os2fragment and an Os4carbido fragment are linked together by a gold atom.

Original language	English
Journal	Journal of Organometallic Chemistry
Volume	401
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(91)86216-D
Publication status	Published - 8 Jan 1991
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/0022-328X(91)86216-D

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title = "Isolation, characterisation, and crystal and molecular structure of [Os6AuC(CO)20(μ-OMe)]",

abstract = "Treatment of [Os3(CO)10(μ-AuPEt3)(μ-COMe)] with [Os3(CO)10(NCMe)2] in refluxing toluene affords the new carbido compound [Os6AuC(CO)20(μ-OMe)] (1). A single-crystal X-ray structure analysis of 1 shows that an Os2fragment and an Os4carbido fragment are linked together by a gold atom.",

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AU - Hay, Caroline M.

AU - Johnson, Brian F.G.

AU - Lewis, Jack

AU - Prior, Neville D.

AU - Raithby, Paul R.

AU - Wong, Wing Tak

PY - 1991/1/8

Y1 - 1991/1/8

N2 - Treatment of [Os3(CO)10(μ-AuPEt3)(μ-COMe)] with [Os3(CO)10(NCMe)2] in refluxing toluene affords the new carbido compound [Os6AuC(CO)20(μ-OMe)] (1). A single-crystal X-ray structure analysis of 1 shows that an Os2fragment and an Os4carbido fragment are linked together by a gold atom.

AB - Treatment of [Os3(CO)10(μ-AuPEt3)(μ-COMe)] with [Os3(CO)10(NCMe)2] in refluxing toluene affords the new carbido compound [Os6AuC(CO)20(μ-OMe)] (1). A single-crystal X-ray structure analysis of 1 shows that an Os2fragment and an Os4carbido fragment are linked together by a gold atom.

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U2 - 10.1016/0022-328X(91)86216-D

DO - 10.1016/0022-328X(91)86216-D

M3 - Journal article

SN - 0022-328X

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JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

Isolation, characterisation, and crystal and molecular structure of [Os₆AuC(CO)₂₀(μ-OMe)]

Abstract

ASJC Scopus subject areas

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