Importance of alkyl chain-length on the self-assembly of new Ni(qdt) 2 complexes and charge transport properties

Xiong Bo Yang; Li Zhou; Long Biao Huang; Jia Ju Xu; Ye Zhou; Su Ting Han; Zong Xiang Xu; Victor C.Y. Lau; Micheal Hon-Wah Lam; Wai Yeung Wong; V. A.L. Roy

doi:10.1039/c3ra41633j

Importance of alkyl chain-length on the self-assembly of new Ni(qdt) ₂ complexes and charge transport properties

Xiong Bo Yang
, Li Zhou
, Long Biao Huang
, Jia Ju Xu
, Ye Zhou
, Su Ting Han
, Zong Xiang Xu
, Victor C.Y. Lau
, Micheal Hon-Wah Lam
, Wai Yeung Wong
, V. A.L. Roy

Research output: Journal article publication › Journal article › Academic research › peer-review

4 Citations (Scopus)

Abstract

A series of ionic complexes composed with ([Ni(qdt)₂] ^2-) and alkyl substituted asymmetric viologen derivatives (AV ⁺) as cations have been synthesized and characterized. A slight change in the length of the alkyl chain of AV⁺ alters the cation-anion packing and leads to different charge transport properties of these complexes. Here, we establish a structure-property relationship of Ni(qdt) ₂ complexes by structurally modifying the cations.

Original language	English
Pages (from-to)	12075-12079
Number of pages	5
Journal	RSC Advances
Volume	3
Issue number	30
DOIs	https://doi.org/10.1039/c3ra41633j
Publication status	Published - 21 May 2013
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

More information

10.1039/c3ra41633j

Cite this

@article{0f5af480c9b8418dbd09f75a09dbd195,

title = "Importance of alkyl chain-length on the self-assembly of new Ni(qdt) 2 complexes and charge transport properties",

abstract = "A series of ionic complexes composed with ([Ni(qdt)2] 2-) and alkyl substituted asymmetric viologen derivatives (AV +) as cations have been synthesized and characterized. A slight change in the length of the alkyl chain of AV+ alters the cation-anion packing and leads to different charge transport properties of these complexes. Here, we establish a structure-property relationship of Ni(qdt) 2 complexes by structurally modifying the cations.",

author = "Yang, \{Xiong Bo\} and Li Zhou and Huang, \{Long Biao\} and Xu, \{Jia Ju\} and Ye Zhou and Han, \{Su Ting\} and Xu, \{Zong Xiang\} and Lau, \{Victor C.Y.\} and \{Hon-Wah Lam\}, Micheal and Wong, \{Wai Yeung\} and Roy, \{V. A.L.\}",

year = "2013",

month = may,

day = "21",

doi = "10.1039/c3ra41633j",

language = "English",

volume = "3",

pages = "12075--12079",

journal = "RSC Advances",

issn = "2046-2069",

publisher = "Royal Society of Chemistry",

number = "30",

}

TY - JOUR

T1 - Importance of alkyl chain-length on the self-assembly of new Ni(qdt) 2 complexes and charge transport properties

AU - Yang, Xiong Bo

AU - Zhou, Li

AU - Huang, Long Biao

AU - Xu, Jia Ju

AU - Zhou, Ye

AU - Han, Su Ting

AU - Xu, Zong Xiang

AU - Lau, Victor C.Y.

AU - Hon-Wah Lam, Micheal

AU - Wong, Wai Yeung

AU - Roy, V. A.L.

PY - 2013/5/21

Y1 - 2013/5/21

N2 - A series of ionic complexes composed with ([Ni(qdt)2] 2-) and alkyl substituted asymmetric viologen derivatives (AV +) as cations have been synthesized and characterized. A slight change in the length of the alkyl chain of AV+ alters the cation-anion packing and leads to different charge transport properties of these complexes. Here, we establish a structure-property relationship of Ni(qdt) 2 complexes by structurally modifying the cations.

AB - A series of ionic complexes composed with ([Ni(qdt)2] 2-) and alkyl substituted asymmetric viologen derivatives (AV +) as cations have been synthesized and characterized. A slight change in the length of the alkyl chain of AV+ alters the cation-anion packing and leads to different charge transport properties of these complexes. Here, we establish a structure-property relationship of Ni(qdt) 2 complexes by structurally modifying the cations.

UR - https://www.scopus.com/pages/publications/84881525952

U2 - 10.1039/c3ra41633j

DO - 10.1039/c3ra41633j

M3 - Journal article

AN - SCOPUS:84881525952

SN - 2046-2069

VL - 3

SP - 12075

EP - 12079

JO - RSC Advances

JF - RSC Advances

IS - 30

ER -

Importance of alkyl chain-length on the self-assembly of new Ni(qdt) ₂ complexes and charge transport properties

Abstract

ASJC Scopus subject areas

More information

Other files and links

Fingerprint

Cite this