Highly efficient asymmetric hydrogenation of α,β-unsaturated carboxylic acids catalyzed by ruthenium(II)-dipyridylphosphine complexes

Liqin Qiu, Yue Ming Li, Fuk Yee Kwong, Wing Yiu Yu, Qing Hua Fan, Albert S C Chan

Research output: Journal article publicationJournal articleAcademic researchpeer-review

23 Citations (Scopus)

Abstract

Two types of catalysts [RuL(benzene)Cl]Cl and Ru(OCOCH3) 2L with the dipyridylphosphine ligands P-Phos and Xyl-P-Phos were applied in the asymmetric hydrogenation of α,β-unsaturated carboxylic acids. The cationic complexes [RuL(benzene)Cl]Cl were found to be superior to the corresponding neutral complex Ru(OCOCH3)2L in this type of reactions. The catalysts exhibited excellent activities and enantioselectivities (up to 97% ee) in the asymmetric hydrogenation. KGaA,.
Original languageEnglish
Pages (from-to)517-520
Number of pages4
JournalAdvanced Synthesis and Catalysis
Volume349
Issue number4-5
DOIs
Publication statusPublished - 1 Mar 2007

Keywords

  • Asymmetric hydrogenation
  • Dipyridylphosphine
  • P-Phos
  • Ruthenium complexes;α,β -unsaturated carboxylic acids
  • Xyl-P-Phos

ASJC Scopus subject areas

  • Chemistry (miscellaneous)
  • Organic Chemistry
  • Catalysis

Cite this