High-yield synthesis of a new layered high-nuclearity carbonyl osmium-rhodium cluster complex - Synthesis, structural characterization, and electrochemistry of [PPN][Os9Rh3(μ-CO)2(CO)26]

Jasmine Po Kwan Lau; Yan Juan Gu; Wing Tak Wong

doi:10.1002/ejic.200700074

High-yield synthesis of a new layered high-nuclearity carbonyl osmium-rhodium cluster complex - Synthesis, structural characterization, and electrochemistry of [PPN][Os₉Rh₃(μ-CO)₂(CO)₂₆]

Jasmine Po Kwan Lau
, Yan Juan Gu
, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

4 Citations (Scopus)

Abstract

A direct and high-yield synthetic route for a novel dodecanuclear osmium-rhodium mixed-metal cluster is presented. The redox properties of the cluster were examined, and it was found that the anion behaves as an "electron reservoir". KGaA, 2007.

Original language	English
Pages (from-to)	3011-3014
Number of pages	4
Journal	European Journal of Inorganic Chemistry
Issue number	19
DOIs	https://doi.org/10.1002/ejic.200700074
Publication status	Published - 20 Jul 2007
Externally published	Yes

Keywords

Electrochemistry
High-nuclearity clusters
Osmium
Rhodium

ASJC Scopus subject areas

Inorganic Chemistry

More information

10.1002/ejic.200700074

Cite this

@article{d55ab851efd74d12a38229920790693c,

title = "High-yield synthesis of a new layered high-nuclearity carbonyl osmium-rhodium cluster complex - Synthesis, structural characterization, and electrochemistry of [PPN][Os9Rh3(μ-CO)2(CO)26]",

abstract = "A direct and high-yield synthetic route for a novel dodecanuclear osmium-rhodium mixed-metal cluster is presented. The redox properties of the cluster were examined, and it was found that the anion behaves as an {"}electron reservoir{"}. KGaA, 2007.",

keywords = "Electrochemistry, High-nuclearity clusters, Osmium, Rhodium",

author = "Lau, \{Jasmine Po Kwan\} and Gu, \{Yan Juan\} and Wong, \{Wing Tak\}",

year = "2007",

month = jul,

day = "20",

doi = "10.1002/ejic.200700074",

language = "English",

pages = "3011--3014",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag",

number = "19",

}

High-yield synthesis of a new layered high-nuclearity carbonyl osmium-rhodium cluster complex - Synthesis, structural characterization, and electrochemistry of [PPN][Os₉Rh₃(μ-CO)₂(CO)₂₆]. / Lau, Jasmine Po Kwan; Gu, Yan Juan; Wong, Wing Tak.
In: European Journal of Inorganic Chemistry, No. 19, 20.07.2007, p. 3011-3014.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

T1 - High-yield synthesis of a new layered high-nuclearity carbonyl osmium-rhodium cluster complex - Synthesis, structural characterization, and electrochemistry of [PPN][Os9Rh3(μ-CO)2(CO)26]

AU - Lau, Jasmine Po Kwan

AU - Gu, Yan Juan

AU - Wong, Wing Tak

PY - 2007/7/20

Y1 - 2007/7/20

N2 - A direct and high-yield synthetic route for a novel dodecanuclear osmium-rhodium mixed-metal cluster is presented. The redox properties of the cluster were examined, and it was found that the anion behaves as an "electron reservoir". KGaA, 2007.

AB - A direct and high-yield synthetic route for a novel dodecanuclear osmium-rhodium mixed-metal cluster is presented. The redox properties of the cluster were examined, and it was found that the anion behaves as an "electron reservoir". KGaA, 2007.

KW - Electrochemistry

KW - High-nuclearity clusters

KW - Osmium

KW - Rhodium

UR - https://www.scopus.com/pages/publications/34447523698

U2 - 10.1002/ejic.200700074

DO - 10.1002/ejic.200700074

M3 - Journal article

SN - 1434-1948

SP - 3011

EP - 3014

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 19

ER -