High-yield synthesis of a new layered high-nuclearity carbonyl osmium-rhodium cluster complex - Synthesis, structural characterization, and electrochemistry of [PPN][Os9Rh3(μ-CO)2(CO)26]

Jasmine Po Kwan Lau, Yan Juan Gu, Wing Tak Wong

Research output: Journal article publicationJournal articleAcademic researchpeer-review

1 Citation (Scopus)

Abstract

A direct and high-yield synthetic route for a novel dodecanuclear osmium-rhodium mixed-metal cluster is presented. The redox properties of the cluster were examined, and it was found that the anion behaves as an "electron reservoir". KGaA, 2007.
Original languageEnglish
Pages (from-to)3011-3014
Number of pages4
JournalEuropean Journal of Inorganic Chemistry
Issue number19
DOIs
Publication statusPublished - 20 Jul 2007
Externally publishedYes

Keywords

  • Electrochemistry
  • High-nuclearity clusters
  • Osmium
  • Rhodium

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this