High-valent dioxo-ruthenium(Vi) complexes of macrocyclic tetradentate tertiary amines: X-ray crystal structures of frans-[Ruvi(15-tmc)02](CIO4)2-(15tmc = 1,4,8,12- tetramethyl-1,4,8,12-tetra-azacyclopentadecane) and trans-[RuVI(16-tmc)o2](CIO4)2 (16-tmc = 1,5,9,13-tetramethyl-1,5,9,13-tetra-azacyclohexadecane)

Thomas C.W. Mak; Chi Ming Che; Kwok Yin Wong

doi:10.1039/C39850000986

High-valent dioxo-ruthenium(Vi) complexes of macrocyclic tetradentate tertiary amines: X-ray crystal structures of frans-[Ru^vi(15-tmc)0₂](CIO₄)₂-(15tmc = 1,4,8,12- tetramethyl-1,4,8,12-tetra-azacyclopentadecane) and trans-[Ru^VI(16-tmc)o₂](CIO₄)₂ (16-tmc = 1,5,9,13-tetramethyl-1,5,9,13-tetra-azacyclohexadecane)

Thomas C.W. Mak
, Chi Ming Che
, Kwok Yin Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

57 Citations (Scopus)

Abstract

The X-ray crystal structures of trans-[Ru^VI(15-tmc)0₂](CIO₄)₂-(15tmc = 1,4,8,12-tetramethyl-1,4,8,12-tetraazacyclopentadecane) and trans-[Ru^VI(16-tmc)O₂](ClO₄)₂ (16-tmc = 1,5,9,13-tetramethyl-1,5,9,13-tetra-azacyclohexadecane) have been determined; the Ru=O bond distances in these two complexes, 1.718(5) and 1.705(7) respectively, appear to be insensitive to the ring size of the macrocycle.

Original language	English
Pages (from-to)	986-988
Number of pages	3
Journal	Journal of the Chemical Society - Series Chemical Communications
Issue number	14
DOIs	https://doi.org/10.1039/C39850000986
Publication status	Published - 1 Jan 1985
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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10.1039/C39850000986

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Mak, T. C. W., Che, C. M., & Wong, K. Y. (1985). High-valent dioxo-ruthenium(Vi) complexes of macrocyclic tetradentate tertiary amines: X-ray crystal structures of frans-[Ru^vi(15-tmc)0₂](CIO₄)₂-(15tmc = 1,4,8,12- tetramethyl-1,4,8,12-tetra-azacyclopentadecane) and trans-[Ru^VI(16-tmc)o₂](CIO₄)₂ (16-tmc = 1,5,9,13-tetramethyl-1,5,9,13-tetra-azacyclohexadecane). Journal of the Chemical Society - Series Chemical Communications, (14), 986-988. https://doi.org/10.1039/C39850000986

Mak, Thomas C.W. ; Che, Chi Ming ; Wong, Kwok Yin. / High-valent dioxo-ruthenium(Vi) complexes of macrocyclic tetradentate tertiary amines: X-ray crystal structures of frans-[Ru^vi(15-tmc)0₂](CIO₄)₂-(15tmc = 1,4,8,12- tetramethyl-1,4,8,12-tetra-azacyclopentadecane) and trans-[Ru^VI(16-tmc)o₂](CIO₄)₂ (16-tmc = 1,5,9,13-tetramethyl-1,5,9,13-tetra-azacyclohexadecane). In: Journal of the Chemical Society - Series Chemical Communications. 1985 ; No. 14. pp. 986-988.

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title = "High-valent dioxo-ruthenium(Vi) complexes of macrocyclic tetradentate tertiary amines: X-ray crystal structures of frans-[Ruvi(15-tmc)02](CIO4)2-(15tmc = 1,4,8,12- tetramethyl-1,4,8,12-tetra-azacyclopentadecane) and trans-[RuVI(16-tmc)o2](CIO4)2 (16-tmc = 1,5,9,13-tetramethyl-1,5,9,13-tetra-azacyclohexadecane)",

abstract = "The X-ray crystal structures of trans-[RuVI(15-tmc)02](CIO4)2-(15tmc = 1,4,8,12-tetramethyl-1,4,8,12-tetraazacyclopentadecane) and trans-[RuVI(16-tmc)O2](ClO4)2 (16-tmc = 1,5,9,13-tetramethyl-1,5,9,13-tetra-azacyclohexadecane) have been determined; the Ru=O bond distances in these two complexes, 1.718(5) and 1.705(7) respectively, appear to be insensitive to the ring size of the macrocycle.",

author = "Mak, \{Thomas C.W.\} and Che, \{Chi Ming\} and Wong, \{Kwok Yin\}",

year = "1985",

month = jan,

day = "1",

doi = "10.1039/C39850000986",

language = "English",

pages = "986--988",

journal = "Journal of the Chemical Society - Series Chemical Communications",

issn = "0022-4936",

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Mak, TCW, Che, CM & Wong, KY 1985, 'High-valent dioxo-ruthenium(Vi) complexes of macrocyclic tetradentate tertiary amines: X-ray crystal structures of frans-[Ru^vi(15-tmc)0₂](CIO₄)₂-(15tmc = 1,4,8,12- tetramethyl-1,4,8,12-tetra-azacyclopentadecane) and trans-[Ru^VI(16-tmc)o₂](CIO₄)₂ (16-tmc = 1,5,9,13-tetramethyl-1,5,9,13-tetra-azacyclohexadecane)', Journal of the Chemical Society - Series Chemical Communications, no. 14, pp. 986-988. https://doi.org/10.1039/C39850000986

High-valent dioxo-ruthenium(Vi) complexes of macrocyclic tetradentate tertiary amines: X-ray crystal structures of frans-[Ru^vi(15-tmc)0₂](CIO₄)₂-(15tmc = 1,4,8,12- tetramethyl-1,4,8,12-tetra-azacyclopentadecane) and trans-[Ru^VI(16-tmc)o₂](CIO₄)₂ (16-tmc = 1,5,9,13-tetramethyl-1,5,9,13-tetra-azacyclohexadecane). / Mak, Thomas C.W.; Che, Chi Ming; Wong, Kwok Yin.
In: Journal of the Chemical Society - Series Chemical Communications, No. 14, 01.01.1985, p. 986-988.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

T1 - High-valent dioxo-ruthenium(Vi) complexes of macrocyclic tetradentate tertiary amines: X-ray crystal structures of frans-[Ruvi(15-tmc)02](CIO4)2-(15tmc = 1,4,8,12- tetramethyl-1,4,8,12-tetra-azacyclopentadecane) and trans-[RuVI(16-tmc)o2](CIO4)2 (16-tmc = 1,5,9,13-tetramethyl-1,5,9,13-tetra-azacyclohexadecane)

AU - Mak, Thomas C.W.

AU - Che, Chi Ming

AU - Wong, Kwok Yin

PY - 1985/1/1

Y1 - 1985/1/1

N2 - The X-ray crystal structures of trans-[RuVI(15-tmc)02](CIO4)2-(15tmc = 1,4,8,12-tetramethyl-1,4,8,12-tetraazacyclopentadecane) and trans-[RuVI(16-tmc)O2](ClO4)2 (16-tmc = 1,5,9,13-tetramethyl-1,5,9,13-tetra-azacyclohexadecane) have been determined; the Ru=O bond distances in these two complexes, 1.718(5) and 1.705(7) respectively, appear to be insensitive to the ring size of the macrocycle.

AB - The X-ray crystal structures of trans-[RuVI(15-tmc)02](CIO4)2-(15tmc = 1,4,8,12-tetramethyl-1,4,8,12-tetraazacyclopentadecane) and trans-[RuVI(16-tmc)O2](ClO4)2 (16-tmc = 1,5,9,13-tetramethyl-1,5,9,13-tetra-azacyclohexadecane) have been determined; the Ru=O bond distances in these two complexes, 1.718(5) and 1.705(7) respectively, appear to be insensitive to the ring size of the macrocycle.

UR - https://www.scopus.com/pages/publications/1542355665

U2 - 10.1039/C39850000986

DO - 10.1039/C39850000986

M3 - Journal article

SN - 0022-4936

SP - 986

EP - 988

JO - Journal of the Chemical Society - Series Chemical Communications

JF - Journal of the Chemical Society - Series Chemical Communications

IS - 14

ER -

Mak TCW, Che CM, Wong KY. High-valent dioxo-ruthenium(Vi) complexes of macrocyclic tetradentate tertiary amines: X-ray crystal structures of frans-[Ru^vi(15-tmc)0₂](CIO₄)₂-(15tmc = 1,4,8,12- tetramethyl-1,4,8,12-tetra-azacyclopentadecane) and trans-[Ru^VI(16-tmc)o₂](CIO₄)₂ (16-tmc = 1,5,9,13-tetramethyl-1,5,9,13-tetra-azacyclohexadecane). Journal of the Chemical Society - Series Chemical Communications. 1985 Jan 1;(14):986-988. doi: 10.1039/C39850000986

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