TY - JOUR
T1 - High-valent dioxo-ruthenium(Vi) complexes of macrocyclic tetradentate tertiary amines: X-ray crystal structures of frans-[Ruvi(15-tmc)02](CIO4)2-(15tmc = 1,4,8,12- tetramethyl-1,4,8,12-tetra-azacyclopentadecane) and trans-[RuVI(16-tmc)o2](CIO4)2 (16-tmc = 1,5,9,13-tetramethyl-1,5,9,13-tetra-azacyclohexadecane)
AU - Mak, Thomas C.W.
AU - Che, Chi Ming
AU - Wong, Kwok Yin
PY - 1985/1/1
Y1 - 1985/1/1
N2 - The X-ray crystal structures of trans-[RuVI(15-tmc)02](CIO4)2-(15tmc = 1,4,8,12-tetramethyl-1,4,8,12-tetraazacyclopentadecane) and trans-[RuVI(16-tmc)O2](ClO4)2 (16-tmc = 1,5,9,13-tetramethyl-1,5,9,13-tetra-azacyclohexadecane) have been determined; the Ru=O bond distances in these two complexes, 1.718(5) and 1.705(7) respectively, appear to be insensitive to the ring size of the macrocycle.
AB - The X-ray crystal structures of trans-[RuVI(15-tmc)02](CIO4)2-(15tmc = 1,4,8,12-tetramethyl-1,4,8,12-tetraazacyclopentadecane) and trans-[RuVI(16-tmc)O2](ClO4)2 (16-tmc = 1,5,9,13-tetramethyl-1,5,9,13-tetra-azacyclohexadecane) have been determined; the Ru=O bond distances in these two complexes, 1.718(5) and 1.705(7) respectively, appear to be insensitive to the ring size of the macrocycle.
UR - http://www.scopus.com/inward/record.url?scp=1542355665&partnerID=8YFLogxK
U2 - 10.1039/C39850000986
DO - 10.1039/C39850000986
M3 - Journal article
SP - 986
EP - 988
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 14
ER -