High-valent dioxo-ruthenium(Vi) complexes of macrocyclic tetradentate tertiary amines: X-ray crystal structures of frans-[Ruvi(15-tmc)02](CIO4)2-(15tmc = 1,4,8,12- tetramethyl-1,4,8,12-tetra-azacyclopentadecane) and trans-[RuVI(16-tmc)o2](CIO4)2 (16-tmc = 1,5,9,13-tetramethyl-1,5,9,13-tetra-azacyclohexadecane)

Thomas C.W. Mak, Chi Ming Che, Kwok Yin Wong

Research output: Journal article publicationJournal articleAcademic researchpeer-review

56 Citations (Scopus)

Abstract

The X-ray crystal structures of trans-[RuVI(15-tmc)02](CIO4)2-(15tmc = 1,4,8,12-tetramethyl-1,4,8,12-tetraazacyclopentadecane) and trans-[RuVI(16-tmc)O2](ClO4)2 (16-tmc = 1,5,9,13-tetramethyl-1,5,9,13-tetra-azacyclohexadecane) have been determined; the Ru=O bond distances in these two complexes, 1.718(5) and 1.705(7) respectively, appear to be insensitive to the ring size of the macrocycle.
Original languageEnglish
Pages (from-to)986-988
Number of pages3
JournalJournal of the Chemical Society - Series Chemical Communications
Issue number14
DOIs
Publication statusPublished - 1 Jan 1985
Externally publishedYes

ASJC Scopus subject areas

  • Molecular Medicine

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