High-efficiency and low-carbon remediation of zinc contaminated sludge by magnesium oxysulfate cement

Binglin Guo, Yongshan Tan, Lei Wang, Liang Chen, Zuliang Wu, Keiko Sasaki, Viktor Mechtcherine, Daniel C.W. Tsang

Research output: Journal article publicationJournal articleAcademic researchpeer-review

3 Citations (Scopus)

Abstract

Electroplating sludge is classified as a hazardous waste due to its extremely high leachability of potentially toxic elements. This study concerns the use of magnesium oxysulfate cement (MOSC) for the stabilisation/solidification (S/S) of Zn-rich electroplating sludge. According to X-ray diffraction and thermogravimetric analyses, Zn was mainly immobilised through both chemical interaction and physical encapsulation in the MOSC hydrates of 5Mg(OH)2·MgSO4.7H2O (5−1−7) phase. The crystal size analysis, elemental mapping, and extended X-ray absorption fine structure (EXAFS) analysis proved that the Zn2+ was also incorporated in the structure of 5–1–7 phase. Unlike Portland cement system, hydration kinetics, setting time, and compressive strength of the MOSC system were only negligibly modified by the presence of Zn, indicating its superior compatibility. Subsequent S/S experiments demonstrated that the MOSC binder exhibited an excellent performance on immobilisation efficiency of Zn (up to 99.9%), as well as satisfying the requirements of setting time and mechanical strength of sludge S/S products. Therefore, MOSC could be an effective and sustainable binder for the treatment of the Zn-rich industrial wastes.

Original languageEnglish
Article number124486
JournalJournal of Hazardous Materials
DOIs
Publication statusAccepted/In press - 2020

Keywords

  • Electroplating sludge
  • Green and sustainable remediation
  • Hazardous waste immobilisation
  • Magnesium oxysulfate cement
  • Metal leachability
  • Stabilisation/solidification

ASJC Scopus subject areas

  • Environmental Engineering
  • Environmental Chemistry
  • Waste Management and Disposal
  • Pollution
  • Health, Toxicology and Mutagenesis

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