Hexagonal microspindle of NH2-MIL-101(Fe) metal-organic frameworks with visible-light-induced photocatalytic activity for the degradation of toluene

Zhiguang Zhang, Xinyong Li, Baojun Liu, Qidong Zhao, Guohua Chen

Research output: Journal article publicationJournal articleAcademic researchpeer-review

96 Citations (Scopus)

Abstract

This work focuses on exploring metal-organic frameworks (MOFs) for degradation of gaseous pollutants. We demonstrate that NH2-MIL-101(Fe) hexagonal micro-spindles, as a new photocatalyst, showed an improved performance for degradation of toluene under visible light irradiation. The structural and optical properties of the as-prepared NH2-MIL-101(Fe) hexagonal micro-spindles were characterized. Furthermore, the catalytic reaction mechanism has been investigated on the basis of in situ Fourier Transform infrared spectroscopy (FTIR) technology. Meanwhile, some intermediates (benzoic acid) and the final product (CO2) of the degradation of toluene were also identified.
Original languageEnglish
Pages (from-to)4289-4295
Number of pages7
JournalRSC Advances
Volume6
Issue number6
DOIs
Publication statusPublished - 1 Jan 2016
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

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