Heteroleptic polypyrazolylborate complexes of the lanthanides: Syntheses and molecular structures of [Nd{HB(pz)3}2Cl(H2O)] (HB(pz)3=hydrotris(pyrazol-1-yl)borate) and [Nd{HB(pz*)3}LCl2] (HB(pz*)3=hydrotris(3,5-dimethylpyrazol-1-yl)borate; L=4,4′-di-tert-butyl-2,2′-bipyridine)

Chao De Sun; Wing Tak Wong

Heteroleptic polypyrazolylborate complexes of the lanthanides: Syntheses and molecular structures of [Nd{HB(pz)₃}₂Cl(H₂O)] (HB(pz)₃=hydrotris(pyrazol-1-yl)borate) and [Nd{HB(pz)₃}LCl₂] (HB(pz)₃=hydrotris(3,5-dimethylpyrazol-1-yl)borate; L=4,4′-di-tert-butyl-2,2′-bipyridine)

Research output: Journal article publication › Journal article › Academic research › peer-review

Abstract

The new heteroleptic hydrotris(pyrazol-1-yl)borate lanthanide complex [Nd{HB(pz)3}2Cl] (1) was prepared from the reaction between anhydrous NdCl3and 2 equiv. of K[HB(pz)3] in THF at room temperature. The H2O adduct of 1, [Nd{HB(pz)3}2Cl(H2O)] · THF (2), is formed when a solution of 1 is allowed to stand at room temperature in the presence of moisture. Reaction of K[HB(pz*)3] with anhydrous NdCl3in the presence of 4,4′-di-tert-butyl-2,2′-bipyridine (L) yields [Nd{HB(Pz*)3}LCl2] (3) in moderate yield. All complexes have been characterized by conventional spectroscopic methods. The molecular structures of 2 and 3 have been determined by X-ray crystallography.

Original language	English
Pages (from-to)	355-360
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	255
Issue number	2
Publication status	Published - 28 Feb 1997
Externally published	Yes

Keywords

Crystal structures
Heteroleptic polypyrazolylborate complexes
Lanthanide complexes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Fingerprint

Dive into the research topics of 'Heteroleptic polypyrazolylborate complexes of the lanthanides: Syntheses and molecular structures of [Nd{HB(pz)₃}₂Cl(H₂O)] (HB(pz)₃=hydrotris(pyrazol-1-yl)borate) and [Nd{HB(pz*)₃}LCl₂] (HB(pz*)₃=hydrotris(3,5-dimethylpyrazol-1-yl)borate; L=4,4′-di-tert-butyl-2,2′-bipyridine)'. Together they form a unique fingerprint.

Cite this

Sun, Chao De ; Wong, Wing Tak. / Heteroleptic polypyrazolylborate complexes of the lanthanides: Syntheses and molecular structures of [Nd{HB(pz)₃}₂Cl(H₂O)] (HB(pz)₃=hydrotris(pyrazol-1-yl)borate) and [Nd{HB(pz*)₃}LCl₂] (HB(pz*)₃=hydrotris(3,5-dimethylpyrazol-1-yl)borate; L=4,4′-di-tert-butyl-2,2′-bipyridine). In: Inorganica Chimica Acta. 1997 ; Vol. 255, No. 2. pp. 355-360.

@article{db92f939810e493287e60c5003fc85cd,

title = "Heteroleptic polypyrazolylborate complexes of the lanthanides: Syntheses and molecular structures of [Nd{HB(pz)3}2Cl(H2O)] (HB(pz)3=hydrotris(pyrazol-1-yl)borate) and [Nd{HB(pz*)3}LCl2] (HB(pz*)3=hydrotris(3,5-dimethylpyrazol-1-yl)borate; L=4,4′-di-tert-butyl-2,2′-bipyridine)",

abstract = "The new heteroleptic hydrotris(pyrazol-1-yl)borate lanthanide complex [Nd{HB(pz)3}2Cl] (1) was prepared from the reaction between anhydrous NdCl3and 2 equiv. of K[HB(pz)3] in THF at room temperature. The H2O adduct of 1, [Nd{HB(pz)3}2Cl(H2O)] · THF (2), is formed when a solution of 1 is allowed to stand at room temperature in the presence of moisture. Reaction of K[HB(pz*)3] with anhydrous NdCl3in the presence of 4,4′-di-tert-butyl-2,2′-bipyridine (L) yields [Nd{HB(Pz*)3}LCl2] (3) in moderate yield. All complexes have been characterized by conventional spectroscopic methods. The molecular structures of 2 and 3 have been determined by X-ray crystallography.",

keywords = "Crystal structures, Heteroleptic polypyrazolylborate complexes, Lanthanide complexes",

author = "Sun, {Chao De} and Wong, {Wing Tak}",

year = "1997",

month = feb,

day = "28",

language = "English",

volume = "255",

pages = "355--360",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier B.V.",

number = "2",

}

Heteroleptic polypyrazolylborate complexes of the lanthanides: Syntheses and molecular structures of [Nd{HB(pz)₃}₂Cl(H₂O)] (HB(pz)₃=hydrotris(pyrazol-1-yl)borate) and [Nd{HB(pz*)₃}LCl₂] (HB(pz*)₃=hydrotris(3,5-dimethylpyrazol-1-yl)borate; L=4,4′-di-tert-butyl-2,2′-bipyridine). / Sun, Chao De; Wong, Wing Tak.
In: Inorganica Chimica Acta, Vol. 255, No. 2, 28.02.1997, p. 355-360.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

T1 - Heteroleptic polypyrazolylborate complexes of the lanthanides: Syntheses and molecular structures of [Nd{HB(pz)3}2Cl(H2O)] (HB(pz)3=hydrotris(pyrazol-1-yl)borate) and [Nd{HB(pz*)3}LCl2] (HB(pz*)3=hydrotris(3,5-dimethylpyrazol-1-yl)borate; L=4,4′-di-tert-butyl-2,2′-bipyridine)

AU - Sun, Chao De

AU - Wong, Wing Tak

PY - 1997/2/28

Y1 - 1997/2/28

N2 - The new heteroleptic hydrotris(pyrazol-1-yl)borate lanthanide complex [Nd{HB(pz)3}2Cl] (1) was prepared from the reaction between anhydrous NdCl3and 2 equiv. of K[HB(pz)3] in THF at room temperature. The H2O adduct of 1, [Nd{HB(pz)3}2Cl(H2O)] · THF (2), is formed when a solution of 1 is allowed to stand at room temperature in the presence of moisture. Reaction of K[HB(pz*)3] with anhydrous NdCl3in the presence of 4,4′-di-tert-butyl-2,2′-bipyridine (L) yields [Nd{HB(Pz*)3}LCl2] (3) in moderate yield. All complexes have been characterized by conventional spectroscopic methods. The molecular structures of 2 and 3 have been determined by X-ray crystallography.

AB - The new heteroleptic hydrotris(pyrazol-1-yl)borate lanthanide complex [Nd{HB(pz)3}2Cl] (1) was prepared from the reaction between anhydrous NdCl3and 2 equiv. of K[HB(pz)3] in THF at room temperature. The H2O adduct of 1, [Nd{HB(pz)3}2Cl(H2O)] · THF (2), is formed when a solution of 1 is allowed to stand at room temperature in the presence of moisture. Reaction of K[HB(pz*)3] with anhydrous NdCl3in the presence of 4,4′-di-tert-butyl-2,2′-bipyridine (L) yields [Nd{HB(Pz*)3}LCl2] (3) in moderate yield. All complexes have been characterized by conventional spectroscopic methods. The molecular structures of 2 and 3 have been determined by X-ray crystallography.

KW - Crystal structures

KW - Heteroleptic polypyrazolylborate complexes

KW - Lanthanide complexes

UR - http://www.scopus.com/inward/record.url?scp=0000082619&partnerID=8YFLogxK

M3 - Journal article

SN - 0020-1693

VL - 255

SP - 355

EP - 360

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 2

ER -