From a blue to white to yellow emitter: A hexanuclear copper iodide nanocluster

Highly emissive copper(i) halide nanoclusters showing thermally activated delayed fluorescence (TADF) have been paid much attention, but rarely reported so far. Herein, a hexanuclear copper(i) iodide cluster containing a tridentate N?P?N ligand, [Cu₆I₆(ppda)₂] {ppda = 2-[2-(dimethylamino)phenyl(phenyl)phosphino]-N,N-dimethylaniline}, was synthesized. All six copper atoms are four-coordinate, including four CuPNI₂and two CuI₄units. This complex exhibits intense white emission in the powder state at room temperature and shows a peak at a wavelength of 535 nm (F_PL= 0.36) with a microsecond lifetime (t= 4.4 µs). Emission colors can be largely tuned from blue to white to yellow, from the crystal to powder to film state at 297 K. The emission of [Cu₆I₆(ppda)₂] originates from a combination of MLCT and XLCT transitions. This complex showed good thermal stability. A solution-processed, nondoped device of complex [Cu₆I₆(ppda)₂] exhibits stable yellow emission with the CIE coordinates (x,y) of (0.43, 0.51). [Cu₆I₆(ppda)₂] also shows reasonable photocatalytic H₂evolution activity under visible-light irradiation.