Franck-Condon simulation of the single vibronic level emission spectra of HSiF and DSiF including anharmonicity

Kam Wah Mok; Edmond P F Lee; Foo Tim Chau; John M. Dyke

doi:10.1063/1.1630559

Franck-Condon simulation of the single vibronic level emission spectra of HSiF and DSiF including anharmonicity

Kam Wah Mok, Edmond P F Lee, Foo Tim Chau, John M. Dyke

Research output: Journal article publication › Journal article › Academic research › peer-review

26 Citations (Scopus)

Abstract

The inclusion of anharmonicity in the theoretical method of FC simulation which has significant effects on the simulated SVL emission spectra of CF2,5and some band sin the photoelectron spectra of F2O and Cl2O. Theoretically, the inclusion of anharmonicity should impove the reliability of the simulated spectra, and generally, simulated spectra including anharmonicity match better with observed spectra than those obtained within the harmonicity oscillator model, as expected.

Original language	English
Pages (from-to)	1292-1305
Number of pages	14
Journal	Journal of Chemical Physics
Volume	120
Issue number	3
DOIs	https://doi.org/10.1063/1.1630559
Publication status	Published - 15 Jan 2004

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1063/1.1630559

http://hdl.handle.net/10397/322

Cite this

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abstract = "The inclusion of anharmonicity in the theoretical method of FC simulation which has significant effects on the simulated SVL emission spectra of CF2,5and some band sin the photoelectron spectra of F2O and Cl2O. Theoretically, the inclusion of anharmonicity should impove the reliability of the simulated spectra, and generally, simulated spectra including anharmonicity match better with observed spectra than those obtained within the harmonicity oscillator model, as expected.",

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AU - Dyke, John M.

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Franck-Condon simulation of the single vibronic level emission spectra of HSiF and DSiF including anharmonicity

Abstract

ASJC Scopus subject areas

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