Framework Isomerism: Highly Augmented Copper(II)-Paddlewheel-Based MOF with Unusual (3,4)-Net Topology

Nianyong Zhu, Debobroto Sensharma, Paul Wix, Matthew J. Lennox, Tina Düren, Wai Yeung Wong, Wolfgang Schmitt

Research output: Journal article publicationJournal articleAcademic researchpeer-review

11 Citations (Scopus)

Abstract

KGaA, Weinheim. The synthesis and structure of a new, highly augmented {Cu2}-"paddlewheel"-based metal-organic framework (MOF) that is stabilized by tritopic benzoate ligands is reported. The structure adopts an uncommon, less symmetrical, (3,4)-connected net topology and represents a rare framework isomer of the extensively studied {Cu2}-based pto and tbo analogues related to the purely inorganic, solid-state structures of platinum oxide or the twisted boracite. The concomitant formation of three isomeric forms by using {Cu}2-"paddlewheel" complexes and a single triangular, trifunctional ligand is unique and stems from the rotational flexibility of the benzoate moieties. Computational analyses support the structural studies and underline that this observed net topology can give rise to an exceptionally high surface area (greater than 3500 m2/g) despite the triple-interpenetrated nature of the compound.
Original languageEnglish
Pages (from-to)1939-1943
Number of pages5
JournalEuropean Journal of Inorganic Chemistry
Volume2016
Issue number13-14
DOIs
Publication statusPublished - 1 May 2016
Externally publishedYes

Keywords

  • Coordination chemistry
  • Copper
  • Metal-organic frameworks
  • Polymorphism
  • Topology

ASJC Scopus subject areas

  • Inorganic Chemistry

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