Formation and reactions of alkylzinc reagents in room-temperature ionic liquids

Man Chun Law; Kwok Yin Wong; Tak Hang Chan

doi:10.1021/jo051772m

Formation and reactions of alkylzinc reagents in room-temperature ionic liquids

Man Chun Law, Kwok Yin Wong, Tak Hang Chan

Research output: Journal article publication › Journal article › Academic research › peer-review

17 Citations (Scopus)

Abstract

The presence of a suitable amount of bromide or chloride ions was found to be critical in forming the alkylzinc reagents from alkyl iodides and zinc metal in the room-temperature ionic liquid, N-butylpyridinium tetrafluoroborate. β-Hydride transfer in the reactions of butylzinc reagents with aldehydes can also be reduced by a bromide ion.

Original language	English
Pages (from-to)	10434-10439
Number of pages	6
Journal	Journal of Organic Chemistry
Volume	70
Issue number	25
DOIs	https://doi.org/10.1021/jo051772m
Publication status	Published - 9 Dec 2005

ASJC Scopus subject areas

Organic Chemistry

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10.1021/jo051772m

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title = "Formation and reactions of alkylzinc reagents in room-temperature ionic liquids",

abstract = "The presence of a suitable amount of bromide or chloride ions was found to be critical in forming the alkylzinc reagents from alkyl iodides and zinc metal in the room-temperature ionic liquid, N-butylpyridinium tetrafluoroborate. β-Hydride transfer in the reactions of butylzinc reagents with aldehydes can also be reduced by a bromide ion.",

author = "Law, {Man Chun} and Wong, {Kwok Yin} and Chan, {Tak Hang}",

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AU - Law, Man Chun

AU - Wong, Kwok Yin

AU - Chan, Tak Hang

PY - 2005/12/9

Y1 - 2005/12/9

N2 - The presence of a suitable amount of bromide or chloride ions was found to be critical in forming the alkylzinc reagents from alkyl iodides and zinc metal in the room-temperature ionic liquid, N-butylpyridinium tetrafluoroborate. β-Hydride transfer in the reactions of butylzinc reagents with aldehydes can also be reduced by a bromide ion.

AB - The presence of a suitable amount of bromide or chloride ions was found to be critical in forming the alkylzinc reagents from alkyl iodides and zinc metal in the room-temperature ionic liquid, N-butylpyridinium tetrafluoroborate. β-Hydride transfer in the reactions of butylzinc reagents with aldehydes can also be reduced by a bromide ion.

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U2 - 10.1021/jo051772m

DO - 10.1021/jo051772m

M3 - Journal article

C2 - 16323854

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VL - 70

SP - 10434

EP - 10439

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 25

ER -

Formation and reactions of alkylzinc reagents in room-temperature ionic liquids

Abstract

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