Fe₃O₄/PMMA with Well-Arranged Structures Synthesized through Magnetic Field-Assisted Atom Transfer Radical Polymerization

Particle- or fiber-reinforced polymer composites with controlled orientations are attracting interest and applications producing innovative materials, biological constructs, and energy devices. To gain the controlled orientations, filed-assisted synthesis is widely selected for its easy operation and control. In this paper, we designed magnetic field-assisted equipment and synthesized a magnetic polymer composite Fe₃O₄/PMMA with a well-arranged layers structure by combining the magnetic field with atom transfer radical polymerization (ATRP). During the polymerization of polymer composites, the magnetic nanoparticles were surrounded by monomers. With the growth of polymer chains, the magnetic particles pushed polymer chains to move according to a specific direction and form a well-arranged structure under the magnetic fields. The existence of a well-arranged layered structure of the composites gives potential guidance for controlling the micro-structure by adding an extra field during the polymerization process. The experimental results provided a possible design to influence the macroscale properties through control of the micro-structure of polymer composites.