Ferromagnetic spin coupling through the 3,4′-biphenyl moiety in Arylamine Oligomers-experimental and computational study

Vincent Maurel; Lukasz Skorka; Nicolas Christophe Orlando Onofrio; Ewa Szewczyk; David Djurado; Lionel Dubois; Jean Marie Mouesca; Irena Kulszewicz-Bajer

doi:10.1021/jp504223v

Ferromagnetic spin coupling through the 3,4′-biphenyl moiety in Arylamine Oligomers-experimental and computational study

Vincent Maurel, Lukasz Skorka, Nicolas Christophe Orlando Onofrio, Ewa Szewczyk, David Djurado, Lionel Dubois, Jean Marie Mouesca, Irena Kulszewicz-Bajer

Research output: Journal article publication › Journal article › Academic research › peer-review

4 Citations (Scopus)

Abstract

This report describes the study of a dimer d2+ and a linear trimer t3+ of amminium radical cations coupled by 3,4′-biphenyl spin coupling units. The synthesis of the parent diamine and triamine and their optical and electrochemical properties obtained by UV-visible and cyclic voltammetry are presented. The chemical doping of the parent diamine d and triamine t was performed quantitatively to obtain samples containing the corresponding dimer d2+ and trimer t3+ in almost pure high-spin states as evidenced by pulsed EPR nutation spectroscopy. The J coupling constants of the corresponding S = 1 and S = 3/2 spin states were measured (J/k = 135 K) and compared quantitatively to DFT calculations.

Original language	English
Pages (from-to)	7657-7667
Number of pages	11
Journal	Journal of Physical Chemistry B
Volume	118
Issue number	27
DOIs	https://doi.org/10.1021/jp504223v
Publication status	Published - 10 Jul 2014
Externally published	Yes

ASJC Scopus subject areas

Surfaces, Coatings and Films
Physical and Theoretical Chemistry
Materials Chemistry

More information

10.1021/jp504223v

Cite this

@article{ac515bc04772483b94e57bcbad562fcc,

title = "Ferromagnetic spin coupling through the 3,4′-biphenyl moiety in Arylamine Oligomers-experimental and computational study",

abstract = "This report describes the study of a dimer d2+ and a linear trimer t3+ of amminium radical cations coupled by 3,4′-biphenyl spin coupling units. The synthesis of the parent diamine and triamine and their optical and electrochemical properties obtained by UV-visible and cyclic voltammetry are presented. The chemical doping of the parent diamine d and triamine t was performed quantitatively to obtain samples containing the corresponding dimer d2+ and trimer t3+ in almost pure high-spin states as evidenced by pulsed EPR nutation spectroscopy. The J coupling constants of the corresponding S = 1 and S = 3/2 spin states were measured (J/k = 135 K) and compared quantitatively to DFT calculations.",

author = "Vincent Maurel and Lukasz Skorka and Onofrio, {Nicolas Christophe Orlando} and Ewa Szewczyk and David Djurado and Lionel Dubois and Mouesca, {Jean Marie} and Irena Kulszewicz-Bajer",

year = "2014",

month = jul,

day = "10",

doi = "10.1021/jp504223v",

language = "English",

volume = "118",

pages = "7657--7667",

journal = "Journal of Physical Chemistry B",

issn = "1520-6106",

publisher = "American Chemical Society",

number = "27",

}

Ferromagnetic spin coupling through the 3,4′-biphenyl moiety in Arylamine Oligomers-experimental and computational study. / Maurel, Vincent; Skorka, Lukasz; Onofrio, Nicolas Christophe Orlando et al.
In: Journal of Physical Chemistry B, Vol. 118, No. 27, 10.07.2014, p. 7657-7667.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

T1 - Ferromagnetic spin coupling through the 3,4′-biphenyl moiety in Arylamine Oligomers-experimental and computational study

AU - Maurel, Vincent

AU - Skorka, Lukasz

AU - Onofrio, Nicolas Christophe Orlando

AU - Szewczyk, Ewa

AU - Djurado, David

AU - Dubois, Lionel

AU - Mouesca, Jean Marie

AU - Kulszewicz-Bajer, Irena

PY - 2014/7/10

Y1 - 2014/7/10

N2 - This report describes the study of a dimer d2+ and a linear trimer t3+ of amminium radical cations coupled by 3,4′-biphenyl spin coupling units. The synthesis of the parent diamine and triamine and their optical and electrochemical properties obtained by UV-visible and cyclic voltammetry are presented. The chemical doping of the parent diamine d and triamine t was performed quantitatively to obtain samples containing the corresponding dimer d2+ and trimer t3+ in almost pure high-spin states as evidenced by pulsed EPR nutation spectroscopy. The J coupling constants of the corresponding S = 1 and S = 3/2 spin states were measured (J/k = 135 K) and compared quantitatively to DFT calculations.

AB - This report describes the study of a dimer d2+ and a linear trimer t3+ of amminium radical cations coupled by 3,4′-biphenyl spin coupling units. The synthesis of the parent diamine and triamine and their optical and electrochemical properties obtained by UV-visible and cyclic voltammetry are presented. The chemical doping of the parent diamine d and triamine t was performed quantitatively to obtain samples containing the corresponding dimer d2+ and trimer t3+ in almost pure high-spin states as evidenced by pulsed EPR nutation spectroscopy. The J coupling constants of the corresponding S = 1 and S = 3/2 spin states were measured (J/k = 135 K) and compared quantitatively to DFT calculations.

UR - http://www.scopus.com/inward/record.url?scp=84904316407&partnerID=8YFLogxK

U2 - 10.1021/jp504223v

DO - 10.1021/jp504223v

M3 - Journal article

SN - 1520-6106

VL - 118

SP - 7657

EP - 7667

JO - Journal of Physical Chemistry B

JF - Journal of Physical Chemistry B

IS - 27

ER -

Ferromagnetic spin coupling through the 3,4′-biphenyl moiety in Arylamine Oligomers-experimental and computational study

Abstract

ASJC Scopus subject areas

More information

Other files and links

Fingerprint

Cite this