Abstract
Cyano-mediated interaction of the alternating high-spin MnIIcenters and low-spin RuIIIcenters in {Mn[Ru(acac)2(CN)2]2}n (Hacac = acetylacetone) results in long-range ferromagnetic ordering below 3.6 K. This novel MnIIRuIIIcoordination polymer, which has a diamond-like structure (see picture), was constructed from [Ru(acac)2(CN)2]- and Mn2+ions.
Original language | English |
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Pages (from-to) | 3031-3033 |
Number of pages | 3 |
Journal | Angewandte Chemie - International Edition |
Volume | 40 |
Issue number | 16 |
DOIs | |
Publication status | Published - 17 Aug 2001 |
Externally published | Yes |
Keywords
- Coordination polymers
- Cyanides
- Magnetic properties
- Manganese
- Ruthenium
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)