Ferromagnetic ordering in a diamond-like cyano-bridged MnIIRuIIIbimetallic coordination polymer

Wai Fun Yeung, Wai Lun Man, Wing Tak Wong, Tai Chu Lau, Song Gao

Research output: Journal article publicationJournal articleAcademic researchpeer-review

95 Citations (Scopus)

Abstract

Cyano-mediated interaction of the alternating high-spin MnIIcenters and low-spin RuIIIcenters in {Mn[Ru(acac)2(CN)2]2}n (Hacac = acetylacetone) results in long-range ferromagnetic ordering below 3.6 K. This novel MnIIRuIIIcoordination polymer, which has a diamond-like structure (see picture), was constructed from [Ru(acac)2(CN)2]- and Mn2+ions.
Original languageEnglish
Pages (from-to)3031-3033
Number of pages3
JournalAngewandte Chemie - International Edition
Volume40
Issue number16
DOIs
Publication statusPublished - 17 Aug 2001
Externally publishedYes

Keywords

  • Coordination polymers
  • Cyanides
  • Magnetic properties
  • Manganese
  • Ruthenium

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

Cite this