Ferromagnetic ordering in a diamond-like cyano-bridged MnIIRuIIIbimetallic coordination polymer

Wai Fun Yeung; Wai Lun Man; Wing Tak Wong; Tai Chu Lau; Song Gao

doi:10.1002/1521-3773(20010817)40:16&lt;3031::AID-ANIE3031&gt;3.0.CO;2-#

Ferromagnetic ordering in a diamond-like cyano-bridged Mn^IIRu^IIIbimetallic coordination polymer

Wai Fun Yeung, Wai Lun Man, Wing Tak Wong, Tai Chu Lau, Song Gao

Research output: Journal article publication › Journal article › Academic research › peer-review

100 Citations (Scopus)

Abstract

Cyano-mediated interaction of the alternating high-spin MnIIcenters and low-spin RuIIIcenters in {Mn[Ru(acac)2(CN)2]2}n (Hacac = acetylacetone) results in long-range ferromagnetic ordering below 3.6 K. This novel MnIIRuIIIcoordination polymer, which has a diamond-like structure (see picture), was constructed from [Ru(acac)2(CN)2]- and Mn2+ions.

Original language	English
Pages (from-to)	3031-3033
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	40
Issue number	16
DOIs	https://doi.org/10.1002/1521-3773(20010817)40:16<3031::AID-ANIE3031>3.0.CO;2-#
Publication status	Published - 17 Aug 2001
Externally published	Yes

Keywords

Coordination polymers
Cyanides
Magnetic properties
Manganese
Ruthenium

ASJC Scopus subject areas

Catalysis
General Chemistry

More information

10.1002/1521-3773(20010817)40:16<3031::AID-ANIE3031>3.0.CO;2-#

Cite this

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title = "Ferromagnetic ordering in a diamond-like cyano-bridged MnIIRuIIIbimetallic coordination polymer",

abstract = "Cyano-mediated interaction of the alternating high-spin MnIIcenters and low-spin RuIIIcenters in {Mn[Ru(acac)2(CN)2]2}n (Hacac = acetylacetone) results in long-range ferromagnetic ordering below 3.6 K. This novel MnIIRuIIIcoordination polymer, which has a diamond-like structure (see picture), was constructed from [Ru(acac)2(CN)2]- and Mn2+ions.",

keywords = "Coordination polymers, Cyanides, Magnetic properties, Manganese, Ruthenium",

author = "Yeung, {Wai Fun} and Man, {Wai Lun} and Wong, {Wing Tak} and Lau, {Tai Chu} and Song Gao",

year = "2001",

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doi = "10.1002/1521-3773(20010817)40:16<3031::AID-ANIE3031>3.0.CO;2-#",

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T1 - Ferromagnetic ordering in a diamond-like cyano-bridged MnIIRuIIIbimetallic coordination polymer

AU - Yeung, Wai Fun

AU - Man, Wai Lun

AU - Wong, Wing Tak

AU - Lau, Tai Chu

AU - Gao, Song

PY - 2001/8/17

Y1 - 2001/8/17

N2 - Cyano-mediated interaction of the alternating high-spin MnIIcenters and low-spin RuIIIcenters in {Mn[Ru(acac)2(CN)2]2}n (Hacac = acetylacetone) results in long-range ferromagnetic ordering below 3.6 K. This novel MnIIRuIIIcoordination polymer, which has a diamond-like structure (see picture), was constructed from [Ru(acac)2(CN)2]- and Mn2+ions.

AB - Cyano-mediated interaction of the alternating high-spin MnIIcenters and low-spin RuIIIcenters in {Mn[Ru(acac)2(CN)2]2}n (Hacac = acetylacetone) results in long-range ferromagnetic ordering below 3.6 K. This novel MnIIRuIIIcoordination polymer, which has a diamond-like structure (see picture), was constructed from [Ru(acac)2(CN)2]- and Mn2+ions.

KW - Coordination polymers

KW - Cyanides

KW - Magnetic properties

KW - Manganese

KW - Ruthenium

UR - http://www.scopus.com/inward/record.url?scp=0035902872&partnerID=8YFLogxK

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DO - 10.1002/1521-3773(20010817)40:16<3031::AID-ANIE3031>3.0.CO;2-#

M3 - Journal article

SN - 1433-7851

VL - 40

SP - 3031

EP - 3033

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 16

ER -