Ferroelectricity and Rashba Effect in a Two-Dimensional Dion-Jacobson Hybrid Organic-Inorganic Perovskite

In Hyeok Park, Qiannan Zhang, Ki Chang Kwon, Ziyu Zhu, Wei Yu, Kai Leng, David Giovanni, Hwa Seob Choi, Ibrahim Abdelwahab, Qing Hua Xu, Tze Chien Sum, Kian Ping Loh

Research output: Journal article publicationJournal articleAcademic researchpeer-review

33 Citations (Scopus)

Abstract

Hybrid organic-inorganic perovskites (HOIPs) are a new generation of high-performance materials for solar cells and light emitting diodes. Beyond these applications, ferroelectricity and spin-related properties of HOIPs are increasingly attracting interests. The presence of strong spin-orbit coupling, allied with symmetry breaking ensured by remanent polarization, should give rise to Rashba-type splitting of electronic bands in HOIP. However, the report of both ferroelectricity and Rashba effect in HOIP is rare. Here we report the observation of robust ferroelectricity and Rashba effect in two-dimensional Dion-Jacobson perovskites.

Original languageEnglish
Pages (from-to)15972-15976
Number of pages5
JournalJournal of the American Chemical Society
Volume141
Issue number40
DOIs
Publication statusPublished - 9 Oct 2019
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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