Facile synthesis and assembly of Cu2S nanodisks to corncoblike nanostructures

Xu Sheng Du, Zhong Zhen Yu, Aravind Dasari, Ma Jun, Yue Zhong Meng, Yiu Wing Mai

Research output: Journal article publicationJournal articleAcademic researchpeer-review

72 Citations (Scopus)

Abstract

The fabrication of haxagonal Cu2S nanocrystals through thermolysis of a copper dithiolate precursor in dodecanethiol and their novel self-assembly structures was investigated. A typical synthesis procedure 0.5 mL of 1,6-hexanedithiol was added slowly to a 25 mL ethanol solution containing 1.2 g of CuCl2. During the dithiol addition the system becomes a slurry because of dithiolate precipitation and after being stirred slowly for 1h the metal dithiolates were separated. The bottle was cooled at room temperature and the resulting brown solution was collected, washed with absolute alcohol several times to remove the byproducts and the excess dodecanethiol and redispersed in ethanol. The SAED pattern was obtained by focusing the electronic beam on the nanodisks. It was observed that the reaction temperature and time both affect the morphology of the Cu2S nanocrystals.

Original languageEnglish
Pages (from-to)5156-5158
Number of pages3
JournalChemistry of Materials
Volume18
Issue number22
DOIs
Publication statusPublished - 31 Oct 2006
Externally publishedYes

ASJC Scopus subject areas

  • General Chemistry
  • General Chemical Engineering
  • Materials Chemistry

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