Facile preparation of hierarchical TiO2nanowire-nanoparticle/nanotube architecture for highly efficient dye-sensitized solar cells

Nianqing Fu, Yan Liu, Yanchun Liu, Wei Lu, Li Min Zhou, Feng Peng, Haitao Huang

Research output: Journal article publicationJournal articleAcademic researchpeer-review

22 Citations (Scopus)

Abstract

In the present work, we developed a facile post-treatment approach, namely one-step hot-water soaking, to the fabrication of double-layer and hierarchical TiO2nanotube arrays (H-TNTAs) comprising a nanoparticle/nanotube hybrid layer and a TiO2nanowire cap layer for highly efficient dye-sensitized solar cells (DSSCs). The nanoparticle/nanotube hybrid structure of the H-TNTA provides enormous specific surface area for sufficient dye attachment and the TiO2nanowire cap layer serves as a light-scattering layer with increased dye-absorption for superior light harvesting efficiency. This engineered integration makes it possible to control the dye-anchoring, charge transport, charge collection, and light scattering within a photoanode simultaneously. The DSSC based on the well tailored architecture yields an exciting power conversion efficiency of 8.21% under 100 mW cm-2, corresponding to 51% improvement as compared with the cell built on the pristine TNTA (P-TNTA, 5.43%). The efficiency can be further improved to 8.82% when the H-TNTA photoanodes are subjected to an additional TiCl4treatment.
Original languageEnglish
Pages (from-to)20366-20374
Number of pages9
JournalJournal of Materials Chemistry A
Volume3
Issue number40
DOIs
Publication statusPublished - 1 Jan 2015

ASJC Scopus subject areas

  • Chemistry(all)
  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

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