Facile generation of L10-FePt nanodot arrays from a nanopatterned metallopolymer blend of iron and platinum homopolymers

Qingchen Dong, Guijun Li, Cheuk Lam Ho, Chi Wah Leung, Philip Wing Tat Pong, Ian Manners, Wai Yeung Wong

Research output: Journal article publicationJournal articleAcademic researchpeer-review

48 Citations (Scopus)

Abstract

Hard ferromagnetic (L10phase) FePt alloy nanoparticles (NPs) with extremely high magnetocrystalline anisotropy are considered to be one of the most promising candidates for the next generation of ultrahigh-density data storage system. The question of how to generate ordered patterns of L10-FePt NPs and how to transform the technology for practical applications represents a key current challenge. Here the direct synthesis of L10phase FePt NPs by pyrolysis of Fe-containing and Pt-containing metallopolymer blend without post-annealing treatment is reported. Rapid single-step fabrication of large-area nanodot arrays (periodicity of 500 nm) of L10-ordered FePt NPs can also be achieved by employing the metallopolymer blend, which possesses excellent solubility in most organic solvents and good solution processability, as the precursor through nanoimprint lithography (NIL). Magnetic force microscopy (MFM) imaging of the nanodot pattern indicates that the patterned L10phase FePt NPs are capable of exhibiting decent magnetic response, which suggests a great potential to be utilized directly in the fabrication of bit patterned media (BPM) for the next generation of magnetic recording technology. Rapid single-step fabrication of large-area nanodot arrays of L10-FePt nanoparticles (NPs) are achieved by employing a metallopolymer blend of individual Fe- and Pt-containing homopolymers as the precursor through nanoimprint lithography. Imaging of the nanodot pattern indicates that the patterned NPs exhibit a decent magnetic response, which suggests potential to be utilized directly in the fabrication of bit-patterned media for the next generation of magnetic recording technology. KGaA, Weinheim.
Original languageEnglish
Pages (from-to)857-862
Number of pages6
JournalAdvanced Functional Materials
Volume24
Issue number6
DOIs
Publication statusPublished - 12 Feb 2014

Keywords

  • bit patterned media
  • FePt nanoparticles
  • magnetic data recording
  • metallopolymers
  • nanoimprint lithography

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Biomaterials
  • Condensed Matter Physics
  • Electrochemistry

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