Fabrication of graphene/MoS2 alternately stacked structure for enhanced lithium storage

Xiaoliang Yu; Jie Tang; Kazuya Terabe; Taizo Sasaki; Runsheng Gao; Yoshikazu Ito; Kensuke Nakura; Kazuko Asano; Masa aki Suzuki

doi:10.1016/j.matchemphys.2019.121987

Fabrication of graphene/MoS₂ alternately stacked structure for enhanced lithium storage

Xiaoliang Yu, Jie Tang, Kazuya Terabe, Taizo Sasaki, Runsheng Gao, Yoshikazu Ito, Kensuke Nakura, Kazuko Asano, Masa aki Suzuki

Research output: Journal article publication › Journal article › Academic research › peer-review

16 Citations (Scopus)

Abstract

Graphene materials have attracted significant research interest as anodes in lithium-ion batteries (LIBs). However, their low volumetric capacity and high working voltage limit the energy density and thus hinder their practical applications. In this research, monolayer graphene and MoS₂ were prepared by controlled CVD growth processes. Graphene/MoS₂ alternately stacked structure (GMASS) was subsequently fabricated by alternately stacking graphene and MoS₂ monolayers layer by layer. When evaluated as an anode for LIB, GMASS demonstrates an obviously reduced working voltage compared to monolayer graphene electrodes (1.31 V vs. 1.46 V). And its volumetric capacity is much higher than that of an average graphite anode (1260 mAh cm⁻³ vs. 461 mAh cm⁻³). This fundamental research could promote the development of graphene/MoS₂ heterostructures for high-energy LIBs.

Original language	English
Article number	121987
Journal	Materials Chemistry and Physics
Volume	239
DOIs	https://doi.org/10.1016/j.matchemphys.2019.121987
Publication status	Published - 1 Jan 2020
Externally published	Yes

Keywords

CVD growth
Graphene/MoS heterostructure
Lithium-ion battery
Volumetric capacity

ASJC Scopus subject areas

General Materials Science
Condensed Matter Physics

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

More information

10.1016/j.matchemphys.2019.121987

Cite this

@article{8360dcf33f4c47358ba74a6c9aaa081c,

title = "Fabrication of graphene/MoS2 alternately stacked structure for enhanced lithium storage",

abstract = "Graphene materials have attracted significant research interest as anodes in lithium-ion batteries (LIBs). However, their low volumetric capacity and high working voltage limit the energy density and thus hinder their practical applications. In this research, monolayer graphene and MoS2 were prepared by controlled CVD growth processes. Graphene/MoS2 alternately stacked structure (GMASS) was subsequently fabricated by alternately stacking graphene and MoS2 monolayers layer by layer. When evaluated as an anode for LIB, GMASS demonstrates an obviously reduced working voltage compared to monolayer graphene electrodes (1.31 V vs. 1.46 V). And its volumetric capacity is much higher than that of an average graphite anode (1260 mAh cm−3 vs. 461 mAh cm−3). This fundamental research could promote the development of graphene/MoS2 heterostructures for high-energy LIBs.",

keywords = "CVD growth, Graphene/MoS heterostructure, Lithium-ion battery, Volumetric capacity",

author = "Xiaoliang Yu and Jie Tang and Kazuya Terabe and Taizo Sasaki and Runsheng Gao and Yoshikazu Ito and Kensuke Nakura and Kazuko Asano and Suzuki, {Masa aki}",

note = "Funding Information: This work was supported by the Panasonic-NIMS Center of Excellence for Advanced Functional Materials . The authors also would like to thank the financial support from JSPS KAKENHI Grant Number JP18H04477 . Publisher Copyright: {\textcopyright} 2019 Elsevier B.V. Copyright: Copyright 2019 Elsevier B.V., All rights reserved.",

year = "2020",

month = jan,

day = "1",

doi = "10.1016/j.matchemphys.2019.121987",

language = "English",

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T1 - Fabrication of graphene/MoS2 alternately stacked structure for enhanced lithium storage

AU - Yu, Xiaoliang

AU - Tang, Jie

AU - Terabe, Kazuya

AU - Sasaki, Taizo

AU - Gao, Runsheng

AU - Ito, Yoshikazu

AU - Nakura, Kensuke

AU - Asano, Kazuko

AU - Suzuki, Masa aki

N1 - Funding Information: This work was supported by the Panasonic-NIMS Center of Excellence for Advanced Functional Materials . The authors also would like to thank the financial support from JSPS KAKENHI Grant Number JP18H04477 . Publisher Copyright: © 2019 Elsevier B.V. Copyright: Copyright 2019 Elsevier B.V., All rights reserved.

PY - 2020/1/1

Y1 - 2020/1/1

N2 - Graphene materials have attracted significant research interest as anodes in lithium-ion batteries (LIBs). However, their low volumetric capacity and high working voltage limit the energy density and thus hinder their practical applications. In this research, monolayer graphene and MoS2 were prepared by controlled CVD growth processes. Graphene/MoS2 alternately stacked structure (GMASS) was subsequently fabricated by alternately stacking graphene and MoS2 monolayers layer by layer. When evaluated as an anode for LIB, GMASS demonstrates an obviously reduced working voltage compared to monolayer graphene electrodes (1.31 V vs. 1.46 V). And its volumetric capacity is much higher than that of an average graphite anode (1260 mAh cm−3 vs. 461 mAh cm−3). This fundamental research could promote the development of graphene/MoS2 heterostructures for high-energy LIBs.

AB - Graphene materials have attracted significant research interest as anodes in lithium-ion batteries (LIBs). However, their low volumetric capacity and high working voltage limit the energy density and thus hinder their practical applications. In this research, monolayer graphene and MoS2 were prepared by controlled CVD growth processes. Graphene/MoS2 alternately stacked structure (GMASS) was subsequently fabricated by alternately stacking graphene and MoS2 monolayers layer by layer. When evaluated as an anode for LIB, GMASS demonstrates an obviously reduced working voltage compared to monolayer graphene electrodes (1.31 V vs. 1.46 V). And its volumetric capacity is much higher than that of an average graphite anode (1260 mAh cm−3 vs. 461 mAh cm−3). This fundamental research could promote the development of graphene/MoS2 heterostructures for high-energy LIBs.

KW - CVD growth

KW - Graphene/MoS heterostructure

KW - Lithium-ion battery

KW - Volumetric capacity

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DO - 10.1016/j.matchemphys.2019.121987

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