Fabrication of 3D Polypyrrole/Graphene Oxide Composite Hydrogels with High Performance Swelling Properties

Xiao She, Peilei Sun, Xianghua Yu, Qiao Zhang, Yanguang Wu, Liang Li, Yineng Huang, Songmin Shang, Shou-xiang Kinor Jiang

Research output: Journal article publicationJournal articleAcademic researchpeer-review

23 Citations (Scopus)

Abstract

The polypyrrole (PPy)/graphene oxide (GO) composite hydrogels with hierarchical porous structures were fabricated by one-step self-assembly method. The static oxidation polymerization of pyrrole monomer in GO aqueous solution resulted in the formation of three-dimensional (3D) PPy/GO composite hydrogels, which consisted of one-dimensional PPy nanofibers and two-dimensional GO nanosheets. The as-prepared composite hydrogels exhibited shrinking-swelling behavior with cycles of suction and water-supplying. The effects of GO nanosheets content on the swelling properties were investigated. Results showed that the well-dispersed GO nanosheets in the hydrogel networks resulted in a significant improvement in water absorbencies of the hydrogels. PPy/GO composite hydrogels exhibited unobvious variation in the water absorbency even in saline solutions. Such excellent properties in water absorbencies endow the conducting 3D PPy/GO composite hydrogels with great potential applications in electrochemical sensors or controlled release.
Original languageEnglish
Pages (from-to)884-889
Number of pages6
JournalJournal of Inorganic and Organometallic Polymers and Materials
Volume24
Issue number5
DOIs
Publication statusPublished - 1 Jan 2014

Keywords

  • Composites
  • Graphene oxide
  • Hydrogel
  • Polypyrrole

ASJC Scopus subject areas

  • Polymers and Plastics
  • Materials Chemistry

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