Exposure to PM_2.5and PAHs from the Tong Liang, China epidemiological study

Chemically speciated PM2.5and particle-bound polycyclic aromatic hydrocarbon (PAH) measurements were made at three sites near urban Tong Liang, Chongqing, a Chinese inland city where coal combustion is used for electricity generation and residential purposes outside of the central city. Ambient sampling was based on 72-hr averages between 3/2/2002 and 2/26/2003. Elevated PM2.5and PAH concentrations were observed at all three sites, with the highest concentrations found in winter and the lowest in summer. This reflects a coupling effect of source variability and meteorological conditions. The PM2.5mass estimated from sulfate, nitrate, ammonium, organics, elemental carbon, crustal material, and salt corresponded with the annual average gravimetric mass within ±10%. Carbonaceous aerosol was the dominant species, while positive correlations between organic carbon and trace elements (e.g., As, Se, Br, Pb, and Zn) were consistent with coal-burning and motor vehicle contributions. Ambient particle-bound PAHs of molecular weight 168-266 were enriched by 1.5 to 3.5 times during the coal-fired power plant operational period. However, further investigation is needed to determine the relative contribution from residential and utility coal combustion and vehicular activities.