Abstract
For the oxy-coal combustion, the accumulation of coal dust in the system has a fire risk of self-ignition. Therefore, understanding the ignition dynamics of coal dust deposits in oxygen-enriched environment is essential for the prevention of fire and dust explosion. In this work, both hot-oven and hot-plate tests were conducted to study the self-ignition behaviour of coal dusts in O2/CO2 ambient with O2 mole fraction from 21% to 50%. Three coal dusts: Indonesian Sebuku coal, Pittsburgh No. 8 coal and South African coal were tested with different sizes. Experimental results revealed that the self-ignition risk increased significantly with the increasing O2 mole fraction: reducing both the critical ignition temperature (10°C in hot-oven test and 40°C in hot-plate test) and the ignition delay time. Comparatively, the inhibiting effect of CO2 was found to be small for self-ignition. In addition, a modified Frank-Kamenetzkii analysis was proposed to explain all measured critical ignition temperatures, and the genetic algorithm was used to determine kinetic parameters of the one-step global reaction. The analysis showed that as the coal maturity/rank increased, both the self-ignition risk and the sensitivity to oxidation decreased, along with the decreasing apparent activation energy and pre-exponential factor. Such trend did not change with the ambient oxygen condition for all three coal dusts. These results improve our understanding of the self-ignition behaviour and the fire risk of coal dust in the oxy-fuel combustion system.
Original language | English |
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Pages (from-to) | 245-254 |
Number of pages | 10 |
Journal | Fuel |
Volume | 160 |
DOIs | |
Publication status | Published - 11 Aug 2015 |
Externally published | Yes |
Keywords
- Critical ignition temperature
- Hot oven
- Hot plate
- Kinetic parameters
- O<inf>2</inf>/CO<inf>2</inf> ambient
- Oxygen rich
ASJC Scopus subject areas
- General Chemical Engineering
- Fuel Technology
- Energy Engineering and Power Technology
- Organic Chemistry