Enhancing the JSC of P3HT-Based OSCs via a Thiophene-Fused Aromatic Heterocycle as a "π-Bridge" for A-π-D-π-A-Type Acceptors

Jiacheng Wang, Tengfei Li, Xiaoxiao Wang, Yiqun Xiao, Cheng Zhong, Jiayu Wang, Kuan Liu, Xinhui Lu, Xiaowei Zhan, Xingguo Chen

    Research output: Journal article publicationJournal articleAcademic researchpeer-review

    22 Citations (Scopus)

    Abstract

    Poly(3-hexylthiophene) (P3HT)-based organic solar cells (OSCs) have been extensively studied due to unique advantages of P3HT such as roll-to-roll and large-area printing fabrication, but a poor short-circuit current density greatly limits the enhancement of power conversion efficiency (PCE). Herein, via the thiophene-fused aromatic heterocycle as a "π-bridge", two "A-π-D-π-A"-type acceptors have been designed and synthesized for P3HT-based OSCs. The aromaticity of the fused thiophene ring has effectively stabilized the quinoid population, thus strengthening the intramolecular charge transfer and further improving the current density. Owing to the weaker electron-withdrawing ability of the thiophene-fused benzotriazole unit in JC2 than the thiophene-fused benzothiadiazole unit in JC1, a blue-shifted absorption occurs for JC2 to show a better complementarity with P3HT to improve the light-harvesting efficiency and current density of the derived OSCs, and an uplifted lowest unoccupied molecular orbital energy level is also achieved for JC2 to obtain higher voltages. Thus, the P3HT:JC2-based device exhibits a PCE of 6.24% with a high JSC of 13.96 mA cm-2 and a VOC of 0.71 V, significantly exceeding those of the P3HT:JC1 device with a PCE of 2.80%, a JSC of 10.66 mA cm-2, and a VOC of 0.48 V. This indicates that the fusion of a thiophene ring onto a benzotriazole unit is an effective strategy to balance the VOC and JSC of P3HT-based OSCs to achieve excellent photovoltaic performances.

    Original languageEnglish
    Pages (from-to)26005-26016
    Number of pages12
    JournalACS Applied Materials and Interfaces
    Volume11
    Issue number29
    DOIs
    Publication statusPublished - 24 Jul 2019

    Keywords

    • A-Ï€-D-Ï€-A type
    • nonfullerene acceptor
    • P3HT
    • photovoltaic performances
    • thiophene-fused aromatic heterocycle

    ASJC Scopus subject areas

    • General Materials Science

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