Engineered Nitrogen-Decorated Carbon Networks for the Metal-Free Catalytic Isomerization of Glucose to Fructose

Season S. Chen, Jack M. Carraher, Giulia Tuci, Andrea Rossin, Caleb A. Raman, Lapo Luconi, Daniel C.W. Tsang, Giuliano Giambastiani, Jean Philippe Tessonnier

Research output: Journal article publicationJournal articleAcademic researchpeer-review

5 Citations (Scopus)

Abstract

Brønsted bases have recently been reported to catalyze the glucose isomerization to fructose. This contribution describes the rational bottom-up approach to the design and synthesis of heterogeneous systems based on a C60 platform surface engineered with catalytically active amino functionalities tethered to carbon nanomaterials within variable (polar/apolar) chemical microenvironments. We demonstrate how carbocatalysts performance for the glucose-to-fructose isomerization may improve depending on amines' neighboring functional groups and their chemical interplay at the C-nanocarrier surface.

Original languageEnglish
Pages (from-to)16959-16963
Number of pages5
JournalACS Sustainable Chemistry and Engineering
Volume7
Issue number20
DOIs
Publication statusPublished - 21 Oct 2019

Keywords

  • Chemical functionalization
  • Functional group synergy
  • Glucose-to-fructose isomerization
  • Metal-free heterogeneous catalysis
  • N-Decorated nanocarbons

ASJC Scopus subject areas

  • Chemistry(all)
  • Environmental Chemistry
  • Chemical Engineering(all)
  • Renewable Energy, Sustainability and the Environment

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